Benzylsulfonylureas and arylsulfamoylureas

ABSTRACT

Benzylsulfonylureas and arylsulfamoylureas are useful as pre-emergent and post-emergent herbicides and as plant growth regulants.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a division of application Ser. No. 886,151, filedJuly 16, 1986, now U.S. Pat. No. 4,746,355 which is a division ofapplication Ser. No. 686,796, filed Dec. 26, 1984, now U.S. Pat. No.4,609,395, which is a continuation-in-part of application Ser. No.585,170, filed on Mar. 1, 1984, now abandoned.

BACKGROUND OF THE INVENTION

European patent application No. 51,466, published May 12, 1982,discloses compounds of the formula ##STR1## where W is a substitutedbenzyl; Z is CH or N; X is CH₃, OCH₃, Cl; and Y is CH₃, C₂ H₅, OCH₃, OC₂H₅, CH₂ OCH₃, NH₂, NHCH₃, or N(CH₃)₂. The compounds are disclosed tohave pre- and post-emergent herbicidal activity and to be useful asplant growth regulators.

European patent application No. 71,441, published Feb. 9, 1983,discloses compounds of the formula ##STR2## where Z is CH or N; X is CH₃or OCH₃ ; Y is Cl, CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂,CH(OCH₃)₂, or ##STR3## and L is ##STR4## where R₁ is H or C₁ -C₃ alkyl;R₂ is H or CH₃, R₅ is H, CH₃, OCH₃, Cl, Br, NO₂, CO₂ R₇, SO₂ R₈, OSO₂R₉, SO₂ NR₁₀ R₁₁ ; R₆ is H or C₁ -C₃ alkyl; R₆ ' is H or CH₃ ; Q is O,S, or SO₂ ; and Q₁ is CR₃ R₄ or O.

Utility as a pre- or post-emergent herbicide and as a plant growthregulant is disclosed.

European patent application No. 79,683, published May 25, 1983,discloses compounds, useful as herbicides or plant growth regulants, ofthe formula ##STR5## where Z is CH or N; X and Y are as in Europeanapplication No. 51,466 (described above) and J is ##STR6## Q is O, S orSO₂ ; R is H or CH₃ ;

R₁ is H, CH₃, OCH₃, Cl, Br, CO₂ R₅, SO₂ R₆, OSO₂ R₇ or SO₂ NR₈ R₉ ;

R₂ and R₃ are independently H or C₁ -C₃ alkyl;

R₄ is H or CH₃ ;

R₅ is C₁ -C₃ alkyl, CH₂ CH═CH₂, CH₂ CH₂ OCH₃ or CH₂ CH₂ Cl;

R₆ is C₁ -C₃ alkyl;

R₇ is C₁ -C₃ alkyl or CF₃ ; and

R₈ and R₉ are independently C₁ -C₂ alkyl.

SUMMARY OF THE INVENTION

The present invention relates to novel compounds of Formula I,agriculturally suitable compositions containing them, and theirmethod-of-use as pre-emergent or post-emergent herbicides or plantgrowth regulants. ##STR7## wherein J is ##STR8## n is 0 or 1; L is CH₂or O;

Q is CH₂ or O;

Q₁ is O, S or SO₂ ;

Q₂ is O or S;

R is H or CH₃ ;

R₁ is H, F, Cl, Br, CH₃ or OCH₃ ;

R₂ is H or C₁ -C₃ alkyl;

R₃ is H or CH₃ ;

R₄ is H or CH₃ ;

R₅ is H, CH₃ or C₂ H₅ ;

R₆ is H or CH₃ ;

R₇ is H or CH₃ ;

R₈ is F, Cl, Br, OCH₃, SCH₃, SO₂ CH₃, CO₂ CH₃, SO₂ N(CH₃)₂ or OSO₂ CH₃ ;

R₉ is H, OH, C₁ -C₆ alkyl, C₁ -C₆ haloalkyl, C₁ -C₆ alkoxyalkyl, C₃ -C₆alkenyl, C₃ -C₆ alkynyl, C₁ -C₆ alkoxy, phenyl, C₃ -C₆ cycloalkyl, C₄-C₇ cycloalkylalkyl, C₁ -C₆ alkylcarbonyl, C₁ -C₆ alkoxycarbonyl,benzyl, C₃ -C₄ haloalkenyl, C₃ -C₆ haloalkynyl, C₃ -C₆alkylcarbonylalkyl, C₃ -C₆ alkoxycarbonylalkyl or C₁ -C₄ cyanoalkyl;

A is ##STR9## X is CH₃, OCH₃, Cl, Br, OCH₂ CF₃ or OCF₂ H; Y is C₁ -C₃alkyl, CH₂ F, cyclopropyl, C.tbd.CH, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃,N(CH₃)₂, OCH₂ CH₂ F, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂OCH₃, CR(OCH₃)₂, ##STR10## CR(OCH₂ CH₃)₂ or OCF₂ H; Z is CH or N;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H;

Y₁ is O or CH₂ ;

X₂ is CH₃, C₂ H₅ or CH₂ CF₃ ;

Y₂ is OCH₃, OC₂ H₅, SCH₃, SC₂ H₅, OCF₂ H, SCF₂ H, CH₃ or CH₂ CH₃ ;

X₃ is CH₃ or OCH₃ ; and

Y₃ is H or CH₃ ;

provided that

(1) when X is Cl or Br, then Z is CH and Y is OCH₃, OC₂ H₅, NHCH₃,N(CH₃)₂ or OCF₂ H; and

(2) when X or Y is OCF₂ H, then Z is CH.

Compounds of formula I that are preferred for reasons of their higherherbicidal activity, greater plant growth regulant activity or morefavorable ease of synthesis are:

(1) Compounds in which A is A-1.

(2) Compounds of the scope of (1) where Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅,CH₂ OCH₃, CH₂ F or CF₃ ; and L is CH₂.

(3) Compounds of the scope of (2) where J is J₁, J₃, J₇, J₈, J₁₅ or J₁₆.

(4) Compounds of the scope of (3) where R is H; R₁ is H; and X is CH₃ orOCH₃.

Compounds that are specifically preferred are

1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide;

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide;

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide;and

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide.

DETAILED DESCRIPTION OF THE INVENTION Synthesis

The compounds of Formula I can be prepared as indicated by one or moreof the methods shown below in Equations 1, 2, 3, and 4.

Equation 1 depicts the reaction of sulfonyl isocyanates of Formula II,where J is other than J₁₉, with the appropriate heterocyclic amines,III, to give the desired products of Formula Ia. ##STR11## wherein J, X,Y and Z are as previously defined, R₂ is C₁ -C₃ alkyl and R₉ is otherthan H or OH.

The reaction of Equation 1 is best carried out in an inert aproticsolvent such as methylene chloride, tetrahydrofuran, or acetonitrile ata temperature between 20° and 80° C. A catalytic amount of1,4-diazabicyclo[2,2,2]octane (DABCO) may be used to accelerate thereaction. In cases in which the products are insoluble in the reactionsolvent, they may be isolated by simple filtration. When the productsare soluble, they may be isolated by evaporation of the solvent andtrituration of the residue with solvents such as 1-chlorobutane, diethylether, or methanol, and filtration.

Compounds of Formula Ib, where J is other than J₃, J₄, J₅, J₆, J₈, J₉,and J₁₂, and where L is --CH₂ --, can be prepared as shown in Equation 2by treating sulfonamides of Formula IV with the methyl ester of apyrimidine or triazinecarbamic acid of Formula V in the presence of anequimolar quantity of trimethylaluminum. ##STR12## wherein X, Y and Zare as previously defined and J is as defined above.

The reaction of Equation 2 is best carried out at temperatures between25° and 83° C. in a solvent such as methylene chloride or1,2-dichloroethane for 12 to 96 hours under an inert atmosphere, astaught in European Pat. No. 84,244 (issued July 27, 1983). The methylcarbamates, V, can be conveniently synthesized by treatment of thecorresponding heterocyclic amines of Formula III with dimethyl carbonateor methyl chloroformate in the presence of a base such as sodium hydrideor pyridine.

Alternatively, compounds of Formula Ic, where J is other than J₅, J₆,J₁₀, and J₁₁, and where L is --CH₂ --, can be prepared as shown below inEquation 3 by the reaction of sulfonamides of Formula IV with the phenylester of the appropriate carbamic acid, VI, in the presence of anequimolar quantity of a tertiary amine base such as1,5-diazabicyclo[5.4.0]undec-5-ene (DBU). ##STR13## wherein J, X, Y andZ are as previously defined.

The reaction shown in Equation 3 is carried out at about 23° C. in asuitable solvent such as dioxane or acetonitrile. Aqueous acid work-upaffords the desired products as described in European patent applicationNo. 70,804 (published Jan. 26, 1983). The phenyl carbamates, VI, can besynthesized by treating the corresponding heterocyclic amines of FormulaIII with diphenyl carbonate or phenyl chloroformate in the presence of abase such as sodium hydride or pyridine.

Compounds of Formula Id, where J is other than J₁₅, J₁₇, and J₁₉, andwhere L is O, can be prepared as shown below in Equation 4. Theintermediate chlorosulfonylurea of Formula VII is formed by treatment ofthe corresponding heterocyclic amine, III, with commercially availablechlorosulfonyl isocyanate and is then allowed to react with anappropriate phenol of Formula VIII. ##STR14## wherein J, X, Y and Z areas previously defined.

The reaction shown in Equation 4 is best carried out according to themethods taught in U.S. Pat. No. 4,391,976.

Sulfonyl isocyanates of Formula IIa, where J is other than J₁₉, and R₂is C₁ -C₃ alkyl, R₉ is other than hydrogen and hydroxy, and where L is--CH₂ --, can be prepared as shown in Equation 5 by the reaction of thecorresponding sulfonamides of general structure IV with phosgene in thepresence of n-butyl isocyanate and a catalytic amount of1,4-diazabicyclo[2.2.2]octane (DABCO). Alternatively, the sulfonylisocyanates, IIa, may be prepared via phosgenation of the appropriaten-butylureas of Formula IX as represented in Equation 6. ##STR15##wherein J is as previously defined.

The reaction shown in Equation 5 is best carried out according to theprocedure described in U.S. Pat. No. 4,238,621. ##STR16## wherein J isas previously defined.

The compounds of Formula IX are conveniently prepared by stirring amixture of the appropriate sulfonamides, IV, anhydrous potassiumcarbonate, and n-butyl isocyanate in acetone or methyl ethyl ketone at25° to 80° C. until all of the isocyanate has reacted. The products areisolated by quenching in dilute mineral acid and recrystallizing thesolid product. The compounds IX are treated with phosgene and acatalytic amount of DABCO in refluxing xylene or chlorobenzene in amanner analogous to that described in Equation 5.

Another method for the preparation of sulfonyl isocyanates IIa is shownin Equation 7. Treatment of sulfonamides of Formula IV with thionylchloride gives intermediate N-sulfinylsulfonamides, X, which affordsulfonyl isocyanates of Formula IIa upon exposure to phosgene in thepresence of a catalytic amount of pyridine. ##STR17## wherein J is aspreviously defined.

The reaction of Equation 7 can best be performed according to theprocedure of H. Ulrich, B. Tucker, and A. Sayigh, J. Org. Chem., 34,3200 (1969).

Sulfonyl isocyanates of Formula IIb, where J is other than J₁₅, J₁₇ orJ₁₉, R₂ is C₁ -C₃ alkyl, R₉ is other than hydrogen and hydroxy, and L isO, can be most easily prepared as shown below in Equation 8 by thereaction of appropriately substituted phenols of Formula VIII withchlorosulfonyl isocyanate. This procedure is taught in U.S. Pat. Nos.4,191,553 and 4,394,153, and by Lohaus in Chem. Ber., 105, 2791 (1972).##STR18## wherein J is as previously defined.

The requisite sulfonamides of Formula IVa can be synthesized from theappropriately substituted benzyl chlorides or benzyl bromides, XI, bythe three-step sequence of reactions outlined below in Equation 9.##STR19## wherein X' is chlorine or bromine;

J is J₁, J₂, J₃, J₁₃, J₁₄, J₁₅, J₁₆, J₂₀, or J₂₁ ;

L is --CH₂ --; and

when J is J₁₅ or J₁₆, Q₁ is SO₂.

Equation 9(a)

The conversion of alkyl halides to isothiouronium salts is wellprecedented in the literature. For relevant examples, see T. B. Johnsonand J. M. Sprague, J. Am. Chem. Soc., 58, 1348 (1936); 59, 1837 and 2439(1937); 61, 176 (1939). In a typical procedure, a benzyl halide ofFormula XI is treated with thiourea in a suitable solvent such asethanol or tetrahydrofuran. Temperatures of 40°-80° C. over one-half to4 hours are typically required to complete the reaction. The productsalts, XII, are isolated by cooling and filtration or by concentrationto remove the solvent. The salts, XII, are generally sufficiently pureto be carried on directly to step (9b) without further purification.

Equation 9(b)

The oxidative chlorination of isothiouronium salts to afford sulfonylchlorides is most conveniently effected according to the procedure ofJohnson as described in J. Am. Chem. Soc., 61, 2548 (1939). Thus, theappropriate isothiouronium salts, XII, are suspended in aqueous aceticacid and treated with at least three equivalents of chlorine attemperatures between 0° and 20° C. The product sulfonyl chlorides ofFormula XIII are isolated by filtration or extraction into methylenechloride followed by drying and evaporation of the solvent. No furtherpurification of the sulfonyl chlorides is necessary.

Equation 9(c)

In Equation (9c), the sulfonyl chlorides of Formula XIII are suspendedin an aprotic solvent such as diethyl ether, 1-chlorobutane, methylenechloride, or tetrahydrofuran and contacted with an excess of anhydrousammonia at a temperature of 0° to 25° C. The product sulfonamides ofFormula IVa are isolated by filtration and washing with water to removethe by-product ammonium chloride, and concentrating the organicsolution. Frequently, the crude sulfonamides may be used directly toprepare the sulfonyl isocyanates of Formula II. However, they may alsobe purified first by recrystallization from a suitable organic solventsuch as ethanol, acetonitrile or chloroform.

Sulfonamides of Formula IVb can be prepared starting from theappropriate benzyl halides of Formula XI by the three-step sequence ofreactions shown below in Equation 10. ##STR20## wherein X' is chlorineor bromine;

J is other than J₂, J₅, J₆, J₁₀ or J₁₁ ; and

L is --CH₂ --.

Equation 10(a)

The displacement reaction of Equation 10(a) is best carried out bytreating the benzyl halides XI with sodium sulfite at reflux temperaturefor 3 to 12 hours in water or aqueous methanol. The solution is cooledand the solvent removed in vacuo to give a residue which is washed withmethanol or ethyl acetate and filtered. Evaporation of the filtrateaffords the sodium sulfonate salt which is typically carried directly onto the next step. For examples of this reaction, see Reed and Tarter, J.Am. Chem. Soc., 57, 571 (1935); and Latimer and Bost, J. Org. Chem., 5,24 (1940).

Equation 10(b)

The reaction shown in Equation 10(b) can be effected by warming amixture of the dried salts of Formula XIV with phosphorous pentachlorideor phosphorous oxychloride according to the procedure of S. Hazlet, J.Am. Chem. Soc., 59, 287 (1937) or O. Billeter, Ber. Deut. Chem. Ges.,38, 2018 (1935). The product sulfonyl chlorides, XIII, are isolatedeither by distillation from the crude reaction mixture or by extractioninto a suitable solvent such as methylene chloride or 1-chlorobutane.

Equation 10(c)

The amination reaction of Equation 10(c) is carried out as describedabove for Equation 9(c).

Benzyl halides of Formulas XIa and XIb (X'=Br or Cl) may be prepared asshown below in Equation 11 by treatment of the appropriately substitutedtoluene derivatives, XV, with either N-bromosuccinimide (NBS) orN-chlorosuccinimide (NCS). ##STR21## wherein X' is chlorine or bromine;

J is J₇, J₈, J₉, J₁₂, J₁₇, J₁₈, J₁₉, J₂₀ or J₂₁ ;

L is --CH₂ --;

R₁ is H, F, Cl, Br or OCH₃ ; and

when J is J₈ or J₁₂, R₃ is H, and

when J is J₁₇, R₃ and R₄ are H.

The reaction of Equation 11 can be most conveniently carried out byheating a solution of the toluene derivatives, XV, and eitherN-bromosuccinimide or N-chlorosuccinimide in a suitable solvent such ascarbon tetrachloride at reflux temperature. A free radical catalyst suchas azoisobutyronitrile or benzoyl peroxide is usually employed toinitiate the reaction. When the reaction is complete, the cooledsolution is filtered to remove the by-product succinimide and thefiltrate concentrated in vacuo. The benzyl halides of Formulas XIa andXIb are often obtained in a sufficiently pure state for furthertransformation.

An alternate method for the preparation of benzyl chlorides of FormulaXIb starting from the appropriate benzyl alcohols of Formula XVI isoutlined below in Equation 12. ##STR22## wherein X' is chlorine;

J is other than J₅, J₆, J₁₀ or J₁₁ ; and

L is --CH₂ --.

There exists a wide variety of well known methods for converting alkylalcohols to the corresponding chlorides. One of the most commonprocedures involves treatment of the alcohols with thionyl chlorideeither alone or in the presence of a suitable base such as pyridine. Forrelevant examples, see the following references: H. Gilman and J. E.Kirby, J. Am. Chem. Soc., 51, 3475 (1929); H. Gilman and A. P. Hewlett,Rec. Trav Chim., 51, 93 (1932); or M. S. Newman, J. Am. Chem. Soc., 62,2295 (1940).

The requisite benzyl alcohols of Formula XVI (shown below in Equation 13for the specific example of J=J₁₆) can be synthesized by reduction ofthe appropriately substituted benzoic acid derivatives of Formula XVIIwith diborane in a solvent such as tetrahydrofuran. ##STR23## whereinR₁, R₃, R₄ and Q₁ are as previously defined.

Although the reaction of Equation 13 is shown specifically for J=J₁₆,this reduction is applicable to ring systems J₁, J₂, J₃, J₄, J₁₃, J₁₄,J₁₅, J₁₈, J₁₉, J₂₀ and J₂₁ where L is --CH₂ --. For a description of theuse of diborane for reduction of benzoic acid derivatives, see H. C.Brown, J. Org. Chem., 38, 2786 (1973).

Alternatively, benzyl alcohols of Formula XVI (shown below in Equation14 for the specific example of J=J₁₆) can be synthesized by reduction ofthe appropriately substituted benzaldehyde derivatives of Formula XVIIIwith sodium borohydride in a solvent such as ethanol. ##STR24## whereinR₁, R₃, R₄ and Q₁ are as previously defined.

Although the reaction of Equation 14 is shown specifically for J=J₁₆,this reduction is applicable to ring systems J₁, J₂, J₃, J₄, J₇, J₈, J₉,J₁₂, J₁₃, J₁₄, J₁₅, J₁₇, J₁₈, J₁₉, J₂₀ and J₂₁ where L is --CH₂ --. Fora description of the use of sodium borohydride for the selectivereduction of aldehydes, see S. Chaikin and W. Brown, J. Am. Chem. Soc.,71, 122 (1949).

The aldehydes of Formula XVIII can be prepared by the procedure shown inEquation 15 starting with the appropriate nitriles of Formula XIX (shownfor the specific example of J=J₁₆). ##STR25## wherein R₁, R₃, R₄ and Q₁are as previously defined.

Although the reaction of Equation 15 is shown specifically for J=J₁₆,this transformation is equally applicable to all of the ring systems(L=--CH₂ --) except J₅, J₆, J₁₀, and J₁₁. The reaction shown in Equation15 can be carried out according to the procedures of H. C. Brown, C. J.Shoaf, and C. P. Garg, Tetrahedron Lett., 9 (1959), and J. A. Marshall,N. H. Andersen, and J. W. Schlicher, J. Org. Chem., 35, 858 (1970).

Benzoic acid derivatives of Formula XVII (shown below in Equation 16 forthe specific example of J=J₁₆) can be prepared by hydrolysis of theappropriate nitriles of Formula XIX which are, in turn, prepared by aSandmeyer reaction on the corresponding aniline derivatives XX.##STR26## wherein R₁, R₃, R₄ and Q₁ are as previously defined.

As before, while the reactions of Equation 16 are shown specifically forJ=J₁₆, these steps are applicable to all ring systems where J is otherthan J₅, J₆, J₁₀ or J₁₁, and L is --CH₂ --.

Equation 16(a)

The diazotization and cuprous cyanide coupling reaction of Equation16(a) is best carried out according to the procedure described inOrganic Syntheses, Coll. Vol. I, p. 514.

Equation 16(b)

Nitriles of Formula XIX are most easily hydrolyzed to the desiredcarboxylic acids XVII by heating at reflux temperature in concentratedsolutions of sulfuric acid or by treatment with 100% phosphoric acid andsubsequent exposure to nitrous acid. The products are typically isolatedby extraction into aqueous base solution followed by washing with asuitable organic solvent such as ether and acidification of the waterlayer. For a compilation of references dealing with this process, see R.Wagner and H. Zook, "Synthetic Organic Chemistry," John Wiley & Sons,Inc., New York, 1953, p. 412.

A method similar to that described in Equation 16 above can be appliedto the synthesis of phenols of Formula VIII as shown below in Equation17 (shown for the specific example of J=J₁₆). ##STR27## wherein R₁, R₃,R₄ and Q₁ are as previously defined.

The reaction of Equation 17 is applicable to ring systems J₁, J₂, J₃,J₄, J₅, J₆, J₇, J₈, J₉, J₁₀, J₁₁, J₁₂, J₁₃, J₁₄, J₁₆, J₁₈, J₂₀ and J₂₁where L is 0. The diazotization and hydrolysis reactions shown inEquation 17 can be carried out according to the following procedures:Stevens and Beutel, J. Am. Chem. Soc., 63, 311 (1941); Grillot andGormley, J. Am. Chem. Soc., 67, 1968 (1945); and Mosettig and Stuart, J.Am. Chem. Soc., 61, 1 (1939).

The requisite aniline derivatives of Formula XX can be prepared in astraightforward manner by reduction of the corresponding nitro compoundsof Formula XXI as shown in Equation 18 (for the example where J=J₁₆).##STR28## wherein R₁, R₃, R₄, and Q are as previously defined.

Although the reaction of Equation 18 is shown specifically for J=J₁₆,this reduction is applicable to all ring systems J₁ -J₂₁. There exists awide variety of methods for effecting the reduction of aromatic nitrogroups to the corresponding aniline derivatives. One of the more commonprocedures involves treating the nitro compounds of Formula XXI with aslight excess of stannous chloride dihydrate in concentratedhydrochloric acid solution at temperatures between 25° and 80° C.Alternatively, reduction may be accomplished with iron powder in glacialacetic acid solution as described by Hazlet and Dornfeld, J. Am. Chem.Soc., 66, 1781 (1944), and by West in J. Chem. Soc., 127, 494 (1925).For a general review, see Groggins, "Unit Processes In OrganicSynthesis," McGraw-Hill Book Co., New York, 1947, pp. 73-128.

Many of the substituted aromatic nitro compounds of Formula XXI (whereit is understood that all ring systems defined in the Summary ofInvention are represented) can be synthesized by methods taught in U.S.patent application Ser. No. 499,443, filed on May 31, 1983, or by any ofseveral possible synthetic routes known to one skilled in the art.

The intermediate functionalized toluene derivatives of Formula XV(L+--CH₂ --) may also be prepared by straightforward synthetic routesknown to one skilled in the art.

The synthesis of heterocyclic amines such as these depicted by FormulaIII has been reviewed in "The Chemistry of Heterocyclic Compounds," aseries published by Interscience Publ., New York and London.Aminopyrimidines are described by D. J. Brown in "The Pyrimidines," Vol.XVI of the series mentioned above. The 2-amino-1,3,5-triazines can beprepared according to the method described by E. M. Smolin and L.Rapaport in "s-Triazines and Derivatives," Vol. XIII.

Agriculturally suitable salts of compounds of Formula I are also usefulherbicides and can be prepared in a number of ways known to the art. Forexample, metal salts can be made by treating compounds of Formula I witha solution of an alkali or alkaline earth metal salt having asufficiently basic anion (e.g., hydroxide, alkoxide, carbonate orhydride). Quaternary amine salts can be made by similar techniques.Detailed examples of such techniques are given in U.S. Pat. No.4,127,405.

The compounds of this invention and their preparation are furtherillustrated by the following examples wherein temperatures are given indegrees centigrade and all parts are by weight unless otherwisedesignated.

EXAMPLE 1 2,6-Dimethylbenzoic acid, methyl ester

A solution of 10 g of 2,6-dimethylbenzoic acid in 22 g thionyl chloridewas stirred at reflux temperature for 2 hours. Removal of the excessthionyl chloride afforded the crude acid chloride as a yellow oil. Thisintermediate was added to a stirred solution of 4 mL of methanol in 10.8mL pyridine at 65°-70° C. After completion of the addition, theresulting mixture was stirred at room temperature for 2 hours and thenpoured into 75 mL ice-water. The aqueous layer was extracted with four50-mL portions of ether and the combined organic extracts wereback-washed with saturated sodium bicarbonate solution, 5% aqueoushydrochloric acid, and water. Drying and evaporation of the solvent gavea pale yellow oil which was purified by bulb-to-bulb distillation(40°-50° C., 0.5 mm Hg) to afford 9.5 g of pure 2,6-dimethylbenzoicacid, methyl ester as a colorless liquid; IR (film) 1725 cm⁻¹ ;NMR(CDCl₃) δ 2.3 (s, 6H), 3.9 (s, 3H), 7.0-7.4 (m, 3H).

EXAMPLE 2 2,6-Bis(α,α'-bromomethyl)benzoic acid, methyl ester

A mixture of 5.0 g of the product from Example 1, 11.1 g ofN-bromosuccinimide and 0.1 g of azoisobutyronitrile in 76 mL carbontetrachloride was heated at reflux temperature for one hour. Thesolution was cooled to room temperature, filtered, and the filtrateconcentrated in vacuo to give a light orange oil. Treatment withether-hexane (1:1, v/v) afforded 3.0 g of pure2,6-bis(α,α'-bromomethyl)benzoic acid, methyl ester as a white solid,m.p. 67°-70° C.; IR(nujol) 1720 cm⁻¹ ; NMR(CDCl₃) δ 4.0 (s, 3H), 4.65(s, 4H), 7.5 (s, 3H).

EXAMPLE 3 7-Bromomethylphthalide

The product from Example 2 (2.0 g) was added to 8 mL of concentratedsulfuric acid and the suspension was warmed to about 60° C. for 3 hours.The solution was allowed to cool and was poured into ice-water. Theresulting white precipitate was collected by filtration, washed wellwith water and dried. Recrystallization from acetone gave 1.0 g of pure7-bromomethylphthalide as a white powder, m.p. 127.5°-131° C.; IR(KBr)1755 cm⁻¹ ; NMR(CDCl₃) δ 5.0 (s, 2H), 5.29 (s, 2H), 7.4 (br d, 1H), 7.5(br d, 1H), 7.6 (dd, 1H).

EXAMPLE 4 7-[[(Amino)(imino)methyl]thiomethyl]phthalide

A solution of 1.0 g of the product from Example 3 in 10 mLtetrahydrofuran was treated with 0.33 g of thiourea and the suspensionwas warmed to reflux temperature for 15 minutes as a thick, whiteprecipitate formed. The reaction mixture was allowed to cool and wasfiltered. The collected solid was washed with 1-chlorobutane and dried.The yield of the pure title compound was 1.2 g as a white powder, m.p.206°-211° C. (dec.); NMR(DMSO-d₆) δ 4.8 (s, 2H), 5.4 (s, 2H), 7.61 (brt, 2H), 7.73 (br t, 1H), 9.1 (brs, 1H), 9.23 (br s, 2H).

EXAMPLE 5 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl chloride

A solution of 9.4 g of the product from Example 4 in 77 mL of 50%aqueous acetic acid was cooled to 0° C. and treated with 8 mL of liquidchlorine. Following the addition, the mixture was stirred at 0°-10° C.for 2 hours, filtered, and the solid was washed well with water. Theyield of 1,3-dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl chloride was5.6 g as an off-white solid, m.p. 103°-105.5° C. (dec); IR(KBr) 1740,1355, 1200 cm⁻¹.

EXAMPLE 6 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonamide

A solution of 5.6 g of the product from Example 5 in 50 mLtetrahydrofuran was cooled to 0° C. under an atmosphere of nitrogen andwas treated with 1.5 mL of anhydrous ammonia. The resulting suspensionwas stirred at room temperature for 3 hours. The insoluble solids werecollected by filtration and were washed with water and dried. The yieldof the title compound was 3.8 g as a white powder, m.p. 192°-195° C.;IR(KBr) 3340, 3240, 1740, 1130 cm⁻¹ ; NMR(DMSO-d₆ /CDCl₃) δ 4.9 (s, 2H),5.4 (s, 2H), 6.7 (br s, 2H) 7.5-7.8 (m, 3H).

EXAMPLE 7 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl isocyanate

A solution of 2.0 g of the product from Example 6 in 25 mL thionylchloride was heated at reflux temperature for 18 hours. The reactionsolution was allowed to cool to room temperature and excess thionylchloride was removed in vacuo. The resulting residue was treated with 16g of 10% phosgene in toluene and 5 drops of pyridine. This mixture wasstirred at reflux temperature for 3 hours. The solution was allowed tocool, filtered under a stream of nitrogen, and the filtrate wasconcentrated to give 1,3-dihydro-1-oxobenzo[c]furan-7-methanesulfonylisocyanate as an orange oil. The infrared spectrum of this compounddisplayed a characteristic isocyanate stretching absorption at 2240 cm⁻¹as well as a carbonyl stretching signal at 1750 cm⁻¹.

EXAMPLE 81,3-Dihydro-N-[(4,6-dimethoxyprimidine-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide

A solution of 8 mmole of the product from Example 7 in 16 mL dryacetonitrile was treated with 1.2 g of 2-amino-4,6-dimethoxypyrimidineand the mixture was heated to 45°-50° C. under an atmosphere of nitrogenfor 2 hours. After being stirred at room temperature for an additional12 hours, the suspension was filtered and the collected solid was washedwell with warm acetonitrile. The yield of the title compound was 1.0 gas a yellow powder, m.p. 181°-184° C. (dec.); IR(KBr) 1765, 1710, 1620,1355 cm⁻¹ ; NMR(CDCl₃) δ 3.83 (s, 6H), 5.27 (s, 2H), 5.41 (s, 2H), 5.76(s, 1H), 7.35 (br s, 1H), 7.5 (m, 1H), 7.7 (m, 2H), 12.4 (br s, 1H).

    ______________________________________                                        General Formulas for Tables 1-7                                               ______________________________________                                        General Formula 1                                                                           ##STR29##                                                       General Formula 1a                                                                          ##STR30##                                                       General Formula 2                                                                           ##STR31##                                                       General Formula 2a                                                                          ##STR32##                                                       General Formula 3                                                                           ##STR33##                                                       General Formula 4                                                                           ##STR34##                                                       General Formula 5                                                                           ##STR35##                                                       General Formula 6                                                                           ##STR36##                                                       General Formula 7                                                                           ##STR37##                                                       ______________________________________                                    

By applying the procedures of Examples 1 through 8, the compounds shownin Tables 1 and 2, following, can be prepared.

                                      TABLE 1                                     __________________________________________________________________________    General Formula 1                                                                                                     m.p.                                  J n L  R.sub.1                                                                            R.sub.9      X     Y        (°C.)                          __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     Br    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CF.sub.3                                       J.sub.1                                                                         1 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub. 2                                                                        H     -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           Cl                                             J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           Cl                                             J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    CH.sub.3     Cl    OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     Br    OCH.sub.3                                      J.sub.1                                                                         0 O  H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H     -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         1 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         5-F  CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-Cl CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-Br CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-CH.sub.3                                                                         CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-OCH.sub.3                                                                        CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                  CH.sub.3                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCHF.sub.2                                                                          OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(CH.sub.3).sub.2                             J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           cyclopropyl                                    J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C.tbd.CH                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           NH.sub.2                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 F                           J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           SCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub. 3                                                                          OCH.sub.2 CH.sub.2 OCH.sub.3                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 C.tbd.CH                             J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           2-methyl-1,3-                                                                 dioxolan-2-yl                                  J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OC.sub.2 H.sub.5).sub.2            J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.1                                                                         0 O  H    CH.sub.3     Cl    NHCH.sub.3                                     J.sub.1                                                                         0 O  H    --CH.sub.2 CN                                                                              OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    --(CH.sub.2).sub.3 CN                                                                      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    OH           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.3 CH(CH.sub.3).sub.2                                                      Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CF.sub.2 H OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH.sub.2 Cl                                                                     Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.5 Cl                                                                      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 OCH.sub.3                                                                       Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH=CH.sub.2                                                                     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH=CHCH.sub.3                                                                   CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.CH                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.C--CH.sub.3                                                               Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 C.tbd.CH                                                                CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --OCH.sub.3  CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --O(CH.sub.2).sub.4 CH.sub.3                                                               Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C.sub.6 H.sub.5                                                                          CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclopropyl  OCH.sub.3                                                                           OCH.sub. 3                                     J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclohexyl   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclopropylmethyl                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclohexylmethyl                                                                           Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C(O)CH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C(O)(CH.sub.2).sub.5 H                                                                   Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CO.sub.2 C.sub.2 H.sub.5                                                                 Br    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CO.sub.2 (CH.sub.2).sub.4 H                                                              Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.sub.6 H.sub.5                                                                 OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 --CH=CH--CH.sub.2 Cl                                                            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.C--CH.sub.2 Cl                                                            Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C(O)CH.sub.3                                                                    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub. 3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    H            Cl    OCH.sub.3                                      J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        Cl    OCH.sub.3                                      J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     Br    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CF.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H     -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         7-Cl CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-Br CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         6-F  CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-CH.sub.3                                                                         CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-OCH.sub.3                                                                        CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                  OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCHF.sub.2                                                                          OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           cyclopropyl                                    J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH=CH.sub.2                          J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5)2                          J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     Cl    NHCH.sub.3                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           --C.tbd.CH                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    OH           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.2 CH(CH.sub.3).sub.2                                                        Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH.sub.2 Cl                                                                       OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.5 Cl                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 OCH.sub.3                                                                         Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.2 OCH.sub.3                                                                 Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH=CH.sub.2                                                                       OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH=CHCH.sub.2 Cl                                                                  CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH=CHCH.sub.3                                                                     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 C.tbd.CCH.sub.3                                                                   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    OCH.sub.3    Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    O(CH.sub.2).sub.4 CH.sub.3                                                                 Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C.sub.6 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    cyclopropyl  Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    cyclopentyl  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C(O)CH.sub.3 OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 C.sub.6 H.sub.5                                                                   Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH=CHCl                                                                           Cl    OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH(CH.sub.3)CO.sub.2 CH.sub.3                                                              Cl    OCH.sub.3                                      __________________________________________________________________________

    TABLE 1a      General Formula 1a J n L Q Q.sub.1 Q.sub.2 R.sub.1 R.sub.2 R.sub.3     R.sub.4 R.sub.5 R.sub.6 R.sub.7 R.sub.8 X Y m.p. (°C.)       J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.3  J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- --     -- Cl OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     Br OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 F     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     CF.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H H -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H C.sub.2 H.sub.5 -- -- -- --  --     -- OCH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H -n-C.sub.3 H.sub.7     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H     CH(CH.sub.3).sub.2 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 1     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- C1 OCH.sub.3 J.sub.2 0     O -- --  -- H CH.sub.3 -- -- -- -- -- -- Br OCH.sub.3 J.sub.2 1 O -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- --     H C.sub.2 H.sub.5 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- 6-Br CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 CH.sub.2 -- -- -- 6-Cl CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- 5-F CH.sub.3 -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- 6-CH.sub.3 CH.sub.3 -- -- -- --     -- -- OCH.sub.3 OCH.sub. 3 J.sub.2 0 O -- -- -- 6-OCH.sub.3 CH.sub.3 --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H     -- -- -- -- OCH.sub.3 OCH.sub.3 181-184,d J.sub.3 0 CH.sub.2 -- -- -- H     -- H H -- -- -- -- CH.sub.3 OCH.sub.3 180-185,d J.sub.3 0 CH.sub.2 -- --     -- H -- H H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H     -- H H -- -- -- -- Cl OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- Cl NHCH.sub.3 J.sub.2 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- Cl OCF.sub.2 H J.sub.2 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.2 CF.sub.3 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCF.sub.2 H OCF.sub.2 H     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     cyclopropyl J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- --  -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).su     b.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     1,3-dioxolan-                2-yl J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(OC.sub.2 H.sub.5).sub.2 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCF.sub.2 H OCH.sub.3 J.sub.2 0 CH.sub.2 --     -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 1,3-dioxolan-     2-yl J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- CH.sub.3 OCH.sub.2     C.tbd.CH J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Br OCH.sub.3     J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 C.sub.2     H.sub.5 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- CH.sub.3     OC.sub.2 H.sub.5 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     CH.sub.3 CH.sub.2 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- --     -- -- OCH.sub.3 CH.sub.2 F J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- --     -- OCH.sub.3 CF.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.3 1 CH.sub.2 --  -- -- H -- CH.sub.3 H -- -- --     -- CH.sub.3 CH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H --     -- -- -- OCH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H     -- -- -- -- Cl OCH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- --     -- CH.sub.3 CH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- -- -- Cl     OCH.sub.3 J.sub.3 0 CH.sub.2 -- --  -- H -- CH.sub.3 H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.3 0 O -- -- -- H -- H H -- -- -- -- Cl OCH.sub.3 J.sub.3 0 O -- --     -- H -- H H -- -- -- -- Br OCH.sub.3 J.sub.3 0 O -- -- -- H -- H H -- --     -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Cl     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 5-F -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 6-Cl -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 6-Br -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 O -- -- -- 5-CH.sub.3 -- H H -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.3 0 O -- -- -- 6-OCH.sub.3 -- H H -- -- -- --  OCH.sub.3     OCH.sub.3 J.sub.3 1 O -- -- -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.4 0 CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.4 1 CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.4 0 O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.4     1 O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.4 0     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.4 0 O -- --     -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 --     -- -- -- -- -- CH.sub.3 CH.sub.3 J.sub.5 0 -- -- -- -- H CH.sub.3 -- --     -- -- -- -- Cl OCH.sub.3 J.sub.5 1 -- -- -- -- H CH.sub.3 -- -- -- -- --     -- OCH.sub.3 OCH.sub.3 J.sub.5 0 -- -- -- -- H H -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 --  -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- --     Cl OCH.sub.3 J.sub.6 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.6 0 -- -- -- -- H H -- -- -- -- -- -- OCH.sub.3 OCH.sub.3      J.sub.6 1 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.8 -- CH.sub.2 --  -- -- H -- H -- -- -- -- -- Cl OCH.sub.3 J.sub.8     -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- Br OCH.sub.3 J.sub.8 --     CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 C.sub.2 H.sub.5     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- CH.sub.3 OC.sub.2     H.sub.5 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3     CH.sub.2 OCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- --     OCH.sub.3 CH.sub.2 F J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- --     OCH.sub.3 CF.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- -- -- -- Cl OCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- 7-Cl -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3      J.sub.9 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.9 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.9     -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.10 -- --     -- -- -- H CH.sub. 3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.10 --     -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl OCH.sub.3 J.sub.10 -- -- --     -- -- H C.sub.2 H.sub.5 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.11     -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.11     -- -- -- -- -- H C.sub.2 H.sub.5 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- Cl OCH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- Br OCH.sub.3     J.sub.12 -- CH.sub.2 -- -- -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.12 -- O -- -- -- H -- H -- -- -- -- -- OCH.sub.3     OCH.sub.3 J.sub.12 -- O -- -- -- H -- H -- -- -- -- -- Cl OCH.sub.3     J.sub.12 -- O -- -- -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.13 -- CH.sub.2 O -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.13 -- CH.sub.2 O -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3     J.sub.13 -- O O -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.13 -- O O -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.13 --     CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3     J.sub.13 -- O CH.sub.2 -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.13 -- O CH.sub.2 -- -- H --  -- -- -- -- -- -- Cl OCH.sub.3     J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3     J.sub.14 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.14 -- O -- -- -- H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.15 --     -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- --     -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- --     O -- H -- HH CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- O --     H -- HH CH.sub.3 -- -- -- Cl OCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- Br OCH.sub.3 J.sub.15 -- -- -- O -- H -- H H     CH.sub.3 -- -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H     -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- -- --     O -- H -- H H C.sub.2 H.sub.5 -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- --     -- O -- H -- CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3     CH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- --     CH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- --     -- Cl OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- --     Br OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- --  -- O -- H -- CH.sub.3 H     CH.sub.3 -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- --     -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 F J.sub.15     -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CF.sub.3     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.3     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- CH.sub.3 CH.sub.3     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- Cl OCH.sub.3 J.sub.15     -- -- -- S -- H -- CH.sub.3 H H -- -- -- Br OCH.sub.3 J.sub.15 -- -- --     S -- H -- H CH.sub.3 CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- --     -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 222-222.5     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.3 208-209 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- --     -- CH.sub.3 CH.sub.3 192-193 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3     H H -- -- --  Cl OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     H -- -- -- Br OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H     -- -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.2 F J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub. 3 CH.sub.3     H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3     CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- --     Cl OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 --     -- -- Br OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2     -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15     -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3     CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 F J.sub.15 -- -- -- SO.sub.2 -- H     -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- OCH.sub. 3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- Cl OCH.sub.3 J.sub.15 -- -- -- SO.sub.2     -- 6-Cl CH.sub.3 H H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- 6-Cl CH.sub.3 H H H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 --     -- -- SO.sub.2 -- 6-Cl CH.sub.3 H H H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- 6-Cl CH.sub.3 H H H -- -- -- Cl OCH.sub.3     J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3     OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 -- -- --     OCH.sub.3 CH.sub.3 J.sub. 15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 --     -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3     -- -- -- Cl OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 --     -- -- Br OCH.sub.3 J.sub.15 -- -- -- O -- 6-Cl -- CH.sub.3 H H -- -- --     OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- 5-Br -- H H CH.sub.3 -- -- --     OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- 6-F -- CH.sub.3 H H -- -- --     OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- 5-CH.sub.3 -- CH.sub.3 H H --     -- -- OCH.sub.3 OCH.sub.3 J.sub.15 --  -- -- O -- 6-OCH.sub.3 --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- S -- 6-Cl --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.16 -- CH.sub.2 -- O -- H     -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.16 -- CH.sub.2 -- S     -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.16 -- O --     SO.sub.2 -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.16 --     O -- SO.sub.2 -- H -- CH.sub.3 H -- -- -- -- Cl OCH.sub.3 J.sub.17 -- --     -- -- O H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.17 -- --     -- -- S H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.17 -- --     -- -- O H -- CH.sub.3 CH.sub.3 -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.17     -- -- -- -- O H -- H H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.18 --     CH.sub.2 -- -- -- H -- H H -- H H -- OCH.sub.3 OCH.sub.3 J.sub.18 --     CH.sub.2 -- -- -- H -- H H -- CH.sub.3 H -- Cl OCH.sub.3 J.sub.18 -- O     -- -- -- H -- H H -- H CH.sub.3 -- OCH.sub.3 OCH.sub.3 J.sub.19 -- -- --     -- -- H -- CH.sub.3 CH.sub.3 -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.19 --      -- -- -- -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.19 -- -- --     -- -- H -- H H -- -- -- -- Cl OCH.sub.3 J.sub.19 -- -- -- -- -- H --     CH.sub.3 CH.sub.3 -- -- -- -- Cl OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- Cl OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H --     -- -- -- -- --  -- CH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- 7-Cl     -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- --     Cl OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- CH.sub.3     CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- F OCH.sub.3     OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl Cl     OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3      CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     SCH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- SO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 --     -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- --  -- -- SO.sub.2      N(CH.sub.3).sub.2 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl Br OCH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 CH.sub.2 F J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl CH.sub.3 OC.sub.2 H.sub.5     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --  Cl OCH.sub.3 C.sub.2     H.sub.5 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- F OCH.sub.3 OCH.sub.3      J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br Cl OCH.sub.3 J.sub.21 --     O -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21     -- O -- -- -- -- -- -- -- -- -- -- SCH.sub.3 OCH.sub.3 OCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2 CH.sub.3 OCH.sub.3     OCH.sub.3 J.sub.21 -- O -- --  --  -- -- -- -- -- -- CO.sub.2 CH.sub.3     OCH.sub.3 OCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2     N(CH.sub.3).sub.2 OCH.sub.3 OCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- --     -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 --     -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 CH.sub.3 OCH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 CH.sub.3     CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2     CH.sub.3 Cl OCH.sub.3 J.sub.21 -- CH.sub.2 --  -- -- -- -- -- -- -- --     -- CO.sub.2 CH.sub.3 Br OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- --     -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 C.sub.2 H.sub.5 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 CH.sub.3     OC.sub.2 H.sub.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     CO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.21 -- CH.sub.2 --     -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.2 F     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3     OCH.sub. 3 CF.sub.3 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.3 J.sub.4 0 CH.sub.2 -- -- -- H -- H     H -- -- -- -- Cl NHCH.sub.3 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- --     -- -- Cl OCF.sub.2 H J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- -- Cl     N(CH.sub.3).sub.2 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 cyclopropyl J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 C.tbd.CH J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.2 CH═CH.sub.2 J.sub.4 0 CH.sub.2 -- -- -- H -- H H     -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.5 0 -- --     -- -- H CH.sub.3 -- -- -- -- -- -- Cl NHCH.sub.3 J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- Cl OCF.sub.2 H J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- Cl N(CH.sub.3).sub.2 J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.5 0 -- -- -- -- H     CH.sub. 3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.5 0 -- --     -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl OCF.sub.2 H     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3     ).sub.2 J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     1,3-dioxolan-                2-yl J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.6 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.6 0 CH.sub.2     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.6 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl N(CH.sub.3).sub.2     J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl N(CH.sub.3).s     ub.2 J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.2 CH.sub.2 F J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 SCH.sub.3 J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.8 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- Cl NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- --     -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- --     -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.8 --     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F     J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 SCH.sub.3     J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 1,3-dioxola     n-                2-yl J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 cyclopropyl J.sub.9 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub. 9 -- O -- -- -- H -- -- -- -- -- --     -- Cl N(CH.sub.3).sub.2 J.sub.9 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- --     -- Cl NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl     OCH.sub.3 J.sub.11 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- Cl     OCH.sub.3 J.sub.11 -- -- -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     NHCH.sub.3 J.sub.12 -- O -- -- -- H -- -- -- --  -- -- -- Cl NHCH.sub.3     J.sub.12 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2      J.sub.12 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-                  2-yl J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- --     -- -- OCH.sub.3 NHCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- --     -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H     -- -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.13 -- CH.sub.2     CH.sub.2 -- -- H -- -- --  -- -- -- -- OCH.sub.3 OCH.sub.2 CH.tbd.CH     J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2     CH═CH.sub.2 J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     CH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.14 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.2 CF.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCHF.sub.2 OCHF.sub.2 J.sub.14 -- CH.sub.2 -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.15 -- -- -- O -- H -- H H H -- -- -- OCH.sub.3     C.tbd.CH J.sub.15 -- -- -- O -- H -- H H H -- -- -- OCH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     OCH.sub.2 CH═CHCl J.sub.15 -- -- -- O -- H -- H H H -- -- -- Cl     NHCH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- -- Cl N(CH.sub.     3).sub.2 J.sub.15 -- -- -- O -- H -- H H CH.sub. 3 -- -- -- OCH.sub.3     cyclopropyl J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H --     -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3     H -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.15 -- -- -- O     -- H -- CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3 SCH.sub.3 J.sub.15 -- --     -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- --     -- S -- H --  CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15     -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 cyclopropyl J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- --     Cl N(CH.sub.3).sub.2 J.sub.15 -- -- -- S -- H -- CH.sub.3 CH.sub.3     CH.sub.3 -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 --     -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- Cl .sub.3 2 N(CH) J.sub.15     -- --  -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2     CH═CH.sub.2 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- --     OCHF.sub.2 SCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H --     -- -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2     -- H -- CH.sub.3 H H -- -- -- CH.sub.3 CH(OCH.sub.3).sub.2 J.sub.16 --     CH.sub.2 -- O -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2     J.sub.16 -- CH.sub.2 -- S -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3     OCH.sub.2 CH═CH.sub.2 J.sub.16 -- O -- SO.sub.2 -- H -- CH.sub.3 H     -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.16 -- O -- SO.sub.2 --     H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3     J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- Cl N(CH.sub.3).sub.2     J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- CH.sub.3 CH(OCH.sub.3)     .sub.2 J.sub.17 -- -- -- -- S H -- CH.sub.3 H -- -- -- -- OCH.sub.3     NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- H H -- OCH.sub.3     NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- CH.sub.3 H -- Cl     N(CH.sub.3).sub.2 J.sub.18 -- O --  -- -- H -- H H -- H CH.sub.3 --     CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H H     -- -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.19 -- -- -- -- -- H --     CH.sub.3 CH.sub.3 -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.19 -- -- -- --     -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.20 -- CH.sub.2     -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.20 --     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 F     J.sub.20 -- O -- -- -- H -- -- --  -- -- -- -- OCH.sub.3 C.tbd.CH     J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub     .2 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Br     OCH.sub.3 N(CH.sub.3).sub.2 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- --     -- -- F OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- OCH.sub.3 OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 C.tbd.CH J.sub.21     -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl Cl NHCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3 NHCH.sub.3     J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 NHCH.sub.     3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2     OCH.sub.3 NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- --     SO.sub.2 CH.sub.3 OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 OCH.sub.3 148-151.5     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3     CH.sub.3 CH.sub.3 191-193.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- --     -- -- CO.sub.2      CH.sub.3 OCH.sub.3 CH.sub.3

                                      TABLE 2                                     __________________________________________________________________________    General Formula 2                                                                                                     m.p.                                  J n L  R.sub.1                                                                            R.sub.9      X     Y        (°C.)                          __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.1                                                                         0 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CF.sub.3                                       J.sub.1                                                                         1 CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            OCH.sub. 3                                     J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    C.sub.2 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H     -n-C.sub.3 H.sub.7                                                                        OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 O  H    CH(CH.sub.3).sub.2                                                                         OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         1 O  H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         5-F  CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         6-Cl CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         6-Br CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-CH.sub.3                                                                         CH.sub. 3    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         6-OCH.sub.3                                                                        CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                  CH.sub.3                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(CH.sub.3)                                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           cyclopropyl                                    J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C.tbd.CH                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           NH.sub.2                                       J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 F                           J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           SCH.sub.3                                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH.sub.2 OCH.sub.3                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 C.tbd.CH                             J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           2-methyl-1,3-                                                                 dioxolan-2-yl                                  J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OC.sub.2 H.sub.5).sub.2            J.sub.1                                                                         0 O  H    CH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.1                                                                         0 O  H    --CH.sub.2 CN                                                                              OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H    --(CH.sub.2).sub.3 CN                                                                      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    OH           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.3 CH(CH.sub.3).sub.2                                                      Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CF.sub.2 H OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH.sub.2 Cl                                                                     Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.5 Cl                                                                      CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 OCH.sub.3                                                                       Cl    OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 OCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH═CH.sub.2                                                                 OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 CH═CHCH.sub.3                                                               CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.CH                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 C.tbd.CH                                                                CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --OCH.sub.3  CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C.sub.6 H.sub.5                                                                          CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclopropyl  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclohexyl   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclopropylmethyl                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    cyclohexylmethyl                                                                           CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C(O)CH.sub.3                                                                             OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --C(O)(CH.sub.2).sub.5 H                                                                   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CO.sub.2 C.sub.2 H.sub.5                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --(CH.sub.2).sub.4 H                                                                       CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.sub. 6 H.sub.5                                                                OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 --CH═CH--CH.sub.2 Cl                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C.tbd.C--CH.sub.2 Cl                                                            CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH.sub.2 C(O)CH.sub.3                                                                    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    --CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 O  H    H            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                         0 CH.sub.2                                                                         H     -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        CH.sub.3                                                                            CH.sub. 3                                      J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           CH.sub.3                                       J.sub.1                                                                         0 O  H     -n-C.sub.4 H.sub.9                                                                        OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H     -n-C.sub.3 H.sub.7                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH(CH.sub.3).sub.2                                                                         CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  H    CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         7-Cl CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-Br CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         6-F  CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-CH.sub.3                                                                         CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              O  7-OCH.sub.3                                                                        CH.sub.3     CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            CH.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C.sub.2 H.sub.5                                J.sub. 7                                                                        --                                                                              CH.sub.2                                                                         H    CH.sub.3     CH.sub.3                                                                            OC.sub.2 H.sub.5                               J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 OCH.sub.3                             J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH.sub.2 F                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CF.sub.3                                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    H            CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C.sub.2 H.sub.5                                                                            CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                  OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           cyclopropyl                                    J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           NHCH.sub.3                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           N(CH.sub.3).sub.2                              J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           OCH.sub.2 CH═CH.sub.2                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH(OCH.sub.3).sub.2                            J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           1,3-dioxolan-                                                                 2-yl                                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           CH(OC.sub.2 H.sub.5).sub.2                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           --C.tbd.CH                                     J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.3     OCH.sub.3                                                                           C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    OH           OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.2 CH(CH.sub.3).sub.2                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH.sub.2 Cl                                                                       OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.5 Cl                                                                        CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 OCH.sub.3                                                                         CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    (CH.sub.2).sub.2 OCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CH.sub.2                                                                   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CHCH.sub.2 Cl                                                              CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CHCH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub. 2 C.tbd.CCH.sub.3                                                                  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    OCH.sub.3    OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    O(CH.sub.2).sub.4 CH.sub.3                                                                 CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    C.sub.6 H.sub.5                                                                            OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    cyclopropyl  CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    cyclopentyl  OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    COCH.sub.3   OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CO.sub.2 CH.sub.3                                                                          OCH.sub.3                                                                           OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 C.sub.6 H.sub.5                                                                   CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH.sub.2 CH═CHCl                                                                       CH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         H    CH(CH.sub.3)CO.sub.2 CH.sub.3                                                              CH.sub.3                                                                            OCH.sub.3                                      __________________________________________________________________________

    TABLE 2a       General Formula 2a J n L Q Q.sub.1 Q.sub.2 R.sub.1 R.sub.2 R.sub.3     R.sub.4 R.sub.5 R.sub.6 R.sub.7 R.sub.8 X Y m.p.(°C.)       J.sub.2 0 CH.sub.2 -- -- -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3     OCH.sub.3  J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- --     -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.2 F     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     CF.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H H -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H C.sub.2 H.sub.5 -- -- -- -- --     -- CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H -n-C.sub.3 H.sub.7     -- --  -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- H     CH(CH.sub.3).sub.2 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 1     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.3     J.sub.2 1 O -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.2 0 O -- -- -- H C.sub.2 H.sub.5 -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- 6-Br CH.sub.3 -- -- -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- 6-Cl CH.sub.3 -- -- -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- -- 5-F CH.sub.3 -- --     -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- 6-CH.sub.3 CH.sub.3     -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.2 0 O -- -- -- 6-OCH.sub.3     CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- --     -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- --     H -- H H -- -- -- -- CH.sub.3 OCH.sub.3 175- 183,d J.sub.3 0 CH.sub.2 --     -- -- H -- H H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- --     H -- H H -- -- -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.3 0 CH.sub.2 -- --     -- H -- H H -- -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.3 0 CH.sub.2 --     -- -- H -- H H -- -- -- -- CH.sub.3 CH.sub.2 OCH.sub.3 J.sub.3 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.2 F J.sub.3 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 CF.sub.3 J.sub.3 1     CH.sub.2 -- -- -- H -- H H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.3 0     CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.3     0 CH.sub.2 -- -- -- H -- H CH.sub.3 -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.3 0 O -- -- -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.3 0     O -- -- -- H -- H H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.3 0 O -- -- -- H     -- H H -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.3 0 O -- -- -- H -- H H --     -- -- -- CH.sub.3 CH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 5-F -- H H -- --     -- -- CH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 6-Cl -- H H -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- 6-Br -- H H -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.3 0 O -- -- -- 5-CH.sub.3 -- H H -- -- --     -- OCH.sub.3 CH.sub.3 J.sub.3 0 O -- -- -- 6-OCH.sub.3 -- H H -- -- --     -- OCH.sub.3 CH.sub.3 J.sub.3 1 O -- -- -- H -- H H -- -- -- -- OCH.sub.3      CH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- -- --     CH.sub.3 CH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- -- --     -- CH.sub.3 OCH.sub.3 J.sub.3 1 CH.sub.2 -- -- -- H -- CH.sub.3 H -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- --     -- CH.sub.3 CH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.3 1 O -- -- -- H -- CH.sub.3 H -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.4 0 CH.sub.2 -- -- -- H -- -- -- -- -- -- --     CH.sub.3 OCH.sub.3 J.sub.4 1 CH.sub.2 -- -- -- H -- -- -- -- -- -- --     CH.sub.3 CH.sub.3 J.sub.4 0 0 -- -- -- H -- -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.4 1 0 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 CH.sub.3     J.sub.5 1 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.5 0 -- -- -- -- H H -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.6 0     -- -- -- -- H CH.sub.3 -- -- -- -- -- --  OCH.sub.3 OCH.sub.3 J.sub.6 0     -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.6 0 --     -- -- -- H H -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.6 1 -- -- -- --     H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.8 -- CH.sub.2 --     -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.8 -- CH.sub.2 --     -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.8 -- CH.sub.2 -- --     -- H -- CH.sub.3 -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.8 -- CH.sub.2     -- -- -- H -- H -- -- -- -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.8 --     CH.sub.2 -- -- -- H -- H -- -- -- -- -- CH.sub.3 OC.sub.2 H.sub.5     J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.2     OCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3     CH.sub.2 F J.sub.8 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3     CF.sub.3 J.sub.8 -- O -- -- -- H -- H -- -- -- -- -- OCH.sub.3 OCH.sub.3     J.sub.8 -- O -- -- -- H -- H -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.8     -- CH.sub.2 -- -- -- 7-Cl -- H -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.9     -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.9     -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.9     -- O -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.10 -- --     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.10 -- --     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.10 -- --     -- -- -- H C.sub.2 H.sub. 5 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.11 -- -- -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3 OCH.sub.3     J.sub.11 -- -- -- -- -- H C.sub.2 H.sub.5 -- -- -- -- -- -- CH.sub.3     OCH.sub.3 J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- --OCH.sub.3     OCH.sub.3 J.sub.12 -- CH.sub.2 -- -- -- H -- H -- -- -- -- -- OCH.sub.3     CH.sub.3 J.sub.12 -- CH.sub.2 -- -- -- H -- CH.sub.3 -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.12 -- O -- -- -- H -- H -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.12 -- O -- -- -- H -- H -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.12 -- O -- -- -- H -- CH.sub.3 -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.13 -- CH.sub.2 O -- -- H -- -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.13 -- CH.sub.2 O -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.13 -- O O -- -- H -- -- -- -- -- -- -- OCH.sub.3      OCH.sub.3 J.sub.13 -- O O -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.13 -- O CH.sub.2 -- -- H -- -- -- -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.13 -- O CH.sub.2 -- -- H -- -- -- -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- --     -- -- OCH.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.14 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 OCH.sub.3 J.sub.14 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- --     CH.sub.3 CH.sub.3 J.sub.15 -- -- -- O -- H -- H H CH.sub.3 -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H -- --     -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H --     -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- --  -- O -- H -- H H     C.sub.2 H.sub.5 -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 CH.sub.3 H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- O     -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- --     -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 --     -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15     -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 C.sub.2     H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H CH.sub.3 -- -- --     CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- -- O -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H     -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 F J.sub.15 -- -- -- O     -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CF.sub.3 J.sub.15 -- --     -- S -- H -- CH.sub.3 H H -- -- --  OCH.sub.3 OCH.sub.3 J.sub.15 -- --     -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- --     S -- H -- CH.sub.3 H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- S --     H -- H CH.sub.3 CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- H H H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub. 3 OCH.sub.3 192-194     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.3 186-187 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- --     -- CH.sub.3 CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H --     -- -- OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- CH.sub.3 OC.sub.2 H.sub.5 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3     CH.sub.2 F J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- -- --     OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 CH.sub.3     H -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3     CH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- --     OCH.sub.3 C.sub.2 H.sub.5 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H     CH.sub.3 -- -- -- CH.sub.3 OC.sub.2 H.sub. 5 J.sub.15 -- -- -- SO.sub.2     -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3 CH.sub.2 OCH.sub.3     J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- -- -- OCH.sub.3      CH.sub.2 F J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H CH.sub.3 -- --     -- OCH.sub.3 CF.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H CH.sub.3 --     -- -- OCH.sub.3 OCH.sub.3 J.sub.15 -- -- -- S -- H -- CH.sub.3 H     CH.sub.3 -- -- -- OCH.sub.3 CH.sub.3 J.sub.15 -- -- -- S -- H --     CH.sub.3 H CH.sub.3 -- -- -- CH.sub.3 CH.sub.3 J.sub.15 -- -- --     SO.sub.2 -- 6-Cl -- CH.sub.3 H H -- -- -- CH.sub.3 CH.sub.3 J.sub.15 --     -- -- SO.sub.2 -- 6-Cl -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 6-Cl -- CH.sub.3 H H -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 5-Br -- H H CH.sub.3 -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 6-F -- CH.sub.3 H H -- -- -- CH.sub.3 OCH.sub.3     J.sub.15 -- -- -- O -- 5-CH.sub.3 -- CH.sub.3 H H -- -- -- CH.sub.3     OCH.sub.3 J.sub.15 -- -- -- O -- 6-OCH.sub.3 -- CH.sub.3 H H -- -- --     CH.sub.3 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- 6-Cl -- CH.sub.3 H H --     -- -- CH.sub.3 OCH.sub.3 J.sub.15 -- -- -- S -- 6-Cl -- CH.sub.3 H H --     -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- CH.sub.2 -- O -- H -- CH.sub.3 H --     -- -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- CH.sub.2 -- S -- H -- H CH.sub.3     -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- O -- SO.sub.2 -- H --     CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.16 -- O -- SO.sub.2 -- H     -- CH.sub.3 H -- -- -- -- CH.sub.3 CH.sub.3 J.sub.17 -- -- -- -- O H --     CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- S H --     CH.sub.3 H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- O H --     CH.sub.3 CH.sub.3 -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.17 -- -- -- -- O     H -- H H -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H     -- H H -- H H -- CH.sub.3 OCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H     H -- CH.sub.3 H -- OCH.sub.3 CH.sub.3 J.sub.18 -- O -- -- -- H -- H H --     H CH.sub.3 -- CH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- CH.sub.3     CH.sub.3 -- -- -- -- CH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H H     -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.19 -- -- -- -- -- H -- H H -- --     -- -- OCH.sub.3 CH.sub.3 J.sub.19 -- -- -- -- -- H -- CH.sub.3 CH.sub.3     -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- CH.sub.3 CH.sub.3 J.sub.20 -- CH.sub.2 -- -- -- 7-Cl -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- --     -- -- -- OCH.sub.3 OCH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 CH.sub.3 J.sub.20 -- O -- -- -- H -- -- -- -- -- -- --     CH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- F     OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl     OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Br     OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- --  -- --     OCH.sub.3 OCH.sub.3 OCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- --     -- -- -- SCH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- --     -- -- -- -- -- -- SO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3     OCH.sub.3 122-122.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 CH.sub.3 J.sub.21 -- CH.sub.2 -- --     -- -- -- -- -- -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21     -- CH.sub.2 -- -- -- -- -- --  -- -- -- -- Cl OCH.sub.3 CF.sub.3     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl CH.sub.3 OC.sub.2     H.sub.5 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     C.sub.2 H.sub.5 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- F OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3     CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.3     CH.sub. 3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SCH.sub.3 OCH.sub.3      CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- SO.sub.2 CH.sub.3     OCH.sub.3 CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- CO.sub.2     CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- --     SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 CH.sub.3 J.sub.21 -- O -- -- -- --     -- -- -- -- -- -- OSO.sub.2 CH.sub.3 OCH.sub.3 CH.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3     CH.sub.3 187-190 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     CO.sub.2 CH.sub.3 CH.sub.3 OC.sub.2 H.sub.5 J.sub.21 -- CH.sub.2 -- --     -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3 CF.sub.3 J.sub.21 --     CH.sub.2 -- -- -- -- -- -- -- -- -- -- CO.sub.2 CH.sub.3 OCH.sub.3     C.sub.2 H.sub.5 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.2 CF.sub.3 OCH.sub.3 J.sub.2 0 CH.sub.2 -- -- --     H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.2 0 CH.sub.2 --     -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.2 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.     2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     OCH.sub.2 CH═CH.sub.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.2 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-                2-yl     J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub. 3     CH(OC.sub.2 H.sub.5).sub.2 J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 -- --     -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.2 0 CH.sub.2 -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.2 0 CH.sub.2     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.3 0     CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3     J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCF.sub.2 H     OCH.sub.3 J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 cyclopropyl J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.3 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.3 0 CH.sub.2 -- --     -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3     J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- CH.sub.3     1,3-dioxolan-                2-yl J.sub.3 0 CH.sub.2 -- -- -- H CH.sub.3     -- -- -- -- -- -- CH.sub.3 OCH.sub.2 C.tbd.CH J.sub.4 0 CH.sub.2 -- --     -- H -- H H -- -- -- -- OCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.3 J.sub.4 0     CH.sub. 2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 cyclopropyl J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.4 0     CH.sub.2 -- -- -- H -- H H -- -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.4 0 CH.sub.2 -- -- -- H -- H H -- -- -- --     OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- --     -- -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.5 0 -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.5 0 -- -- -- -- H CH.sub.3 --     -- -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.5 0 -- -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.5 0 --     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.5 0 --     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2     J.sub.5 0 -- -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan     -                2-yl J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.6 0 CH.sub.2 -- -- -- H     CH.sub.3 -- -- -- -- -- -- OCH.sub.3 cyclopropyl J.sub.6 0 CH.sub.2 --     -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.6 0 CH.sub.2     -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F     J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- -- OCH.sub.3     SCH.sub.3 J.sub.6 0 CH.sub.2 -- -- -- H CH.sub.3 -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- --     -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.8 -- CH.sub.2 --  -- -- H -- -- --     -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.8 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.8 -- CH.sub.2 -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.8 -- CH.sub.2 -- -- -- H     -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 C.tbd.CH J.sub.8 -- CH.sub.2 --     -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.8 --     CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 SCH.sub.3 J.sub.8 --     CH.sub.2 -- -- -- H --  -- -- -- -- -- -- OCH.sub.3 1,3-dioxolan-             2-yl J.sub.8 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 cyclopropyl J.sub.9 -- O -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.9 -- O -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.9 -- O -- -- -- H -- -- -- -- -- --     -- OCH.sub.3 NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- -- --     -- -- OCH.sub.3 NHCH.sub.3 J.sub.10 -- -- -- -- -- H CH.sub.3 -- -- --     -- -- -- CH.sub.3 CH(OCH.sub.3).sub.2 J.sub.11 -- -- -- -- -- H CH.sub.3     -- -- -- -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.11 -- -- -- -- --     H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.12 -- O -- -- -- H --     -- -- -- -- -- -- CH.sub.3 NHCH.sub.3 J.sub.12 -- O -- -- -- H -- -- --     -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.12 -- O -- -- -- H -- --     -- -- -- -- -- OCH.sub.3 1,3-dioxolan-                2-yl J.sub.13 --     CH.sub.2 CH.sub.2 --  -- H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3     J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- -- OCH.sub.3     SCH.sub.3 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H -- -- -- -- -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.13 -- CH.sub.2 CH.sub.2 -- -- H --     -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH.tbd.CH J.sub.14 -- CH.sub.2 --     -- -- H -- -- -- -- -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2     J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.2     CH.sub.2      F J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.2     CF.sub.3 OCH.sub.3 J.sub.14 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- --     OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- O -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2 J.sub.15 -- --     -- O -- H -- H H H -- -- -- OCH.sub.3 C.tbd.CH J.sub.15 -- -- -- O -- H     -- H H H -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.15 -- -- -- O --     H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 CH═ CHCl J.sub.15 --     -- -- O -- H -- H H H -- -- -- CH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- O     -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15 -- --     -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 cyclopropyl J.sub.15 -- --     -- O -- H -- H H CH.sub.3 -- -- -- OCH.sub.3 CH(OCH.sub.3).sub.2     J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3     NHCH.sub.3 J.sub.15 -- -- -- O -- H -- CH.sub.3 CH.sub.3 H -- -- --     OCH.sub.3 CH(OCH.sub.3).sub.2 J.sub.15 -- -- -- O -- H -- CH.sub.3 H H     -- -- -- OCH.sub. 3 OCH.sub.2 C.tbd.CH J.sub.15 -- -- -- O -- H --     CH.sub.3 CH.sub.3 H -- -- -- OCH.sub.3 SCH.sub.3 J.sub.15 -- -- -- S --     H -- CH.sub.3 H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- S -- H     -- CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15 -- -- -- S     -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2 CH═CH.sub.2     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 cyclopropyl     J.sub.15 -- -- -- S -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).s     ub.2 J.sub.15 -- -- -- S -- H -- CH.sub.3 CH.sub.3 CH.sub.3 -- -- --     OCH.sub.3 CH(CH.sub.3).sub.2 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3     H H -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H --     CH.sub.3 H H -- -- -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.15 -- -- --     SO.sub.2 -- H -- CH.sub.3 H H -- -- -- OCH.sub.3 OCH.sub.2      CH═CH.sub.2 J.sub.15 -- -- -- SO.sub.2 -- H -- CH.sub.3 H H -- --     -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.15 -- -- -- SO.sub.2 -- H     -- CH.sub.3 H H -- -- -- CH.sub.3 CH(OCH.sub.3).sub.2 J.sub.16 --     CH.sub.2 -- O -- H -- CH.sub.3 H -- -- -- -- OCH.sub.3 N(CH.sub.3).sub.2     J.sub. 16 -- CH.sub.2 -- S -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3     OCH.sub.2 CH═CH.sub.2 J.sub.16 -- O -- SO.sub.2 -- H -- CH.sub.3 H     -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.16 -- O -- SO.sub.2 --     H -- CH.sub.3 H -- -- -- -- OCH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3     J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- OCH.sub.3 N(CH.sub.3).     sub.2 J.sub.17 -- -- -- -- O H -- CH.sub.3 H -- -- -- -- CH.sub.3     CH(OCH.sub.3).sub.2 J.sub.17 -- -- -- -- S H -- CH.sub.3 H -- -- -- --     OCH.sub.3 NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- H H --     OCH.sub.3 NHCH.sub.3 J.sub.18 -- CH.sub.2 -- -- -- H -- H H -- CH.sub.3     H -- OCH.sub.3 N(CH.sub.3).sub.2 J.sub.18 -- O -- -- -- H -- H H -- H     CH.sub.3 -- CH.sub.3 OCH.sub.2 CH.sub.2 OCH.sub.3 J.sub.19 -- -- -- --     -- H -- H H -- -- -- -- CH.sub.3 OCH.sub.2 CH.sub.2 F J.sub.19 -- -- --     -- -- H -- CH.sub.3 CH.sub.3 -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.19     -- -- -- -- -- H -- H CH.sub.3 -- -- -- -- OCH.sub.3 C.tbd.CH J.sub.20     -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- OCH.sub.3 NHCH.sub.3 J.sub.     20 -- CH.sub.2 -- -- -- H -- -- -- -- -- -- -- CH.sub.3 OCH.sub.2     CH.sub.2 F J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     C.tbd.CH J.sub.20 -- O -- -- -- H -- -- -- -- -- -- -- OCH.sub.3     CH(OCH.sub.3).sub.2 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- --     Cl OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- --     -- Br OCH.sub.3 N(CH.sub.3).sub.2 J.sub.21 -- CH.sub.2 -- -- -- -- -- --     -- -- -- -- F OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- -- -- -- --     -- -- -- -- -- OCH.sub.3 OCH.sub.3 NHCH.sub.3 J.sub.21 -- CH.sub.2 -- --     -- -- -- -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 C.tbd.CH     J.sub.21 -- CH.sub.2 -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3 OCH.sub.2      CH.sub.2 F J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Cl OCH.sub.3     NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- Br OCH.sub.3     NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- -- OCH.sub.3     OCH.sub.3 NHCH.sub.3 J.sub.21 -- O -- -- -- -- -- -- -- -- -- --     SO.sub.2 N(CH.sub.3).sub.2 OCH.sub.3 NHCH.sub.3 J.sub.21 -- O -- -- --     -- -- -- -- -- -- -- SO.sub.2      CH.sub.3 OCH.sub.3 NHCH.sub.3

                                      TABLE 3                                     __________________________________________________________________________    General Formula 3                                                                                                               m.p.                        J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.1                                                                            Y.sub.1                                                                          (°C.)                __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          O                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           O                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.2                       J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OC.sub.2 H.sub.5                                                                   O                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                                                                        O                              J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.2                       J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           O                              J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                                                                        O                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCF.sub.2 H                                                                        O                              J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCF.sub.2 H                                                                        O                              J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                                                                   O                              J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.2                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           O                              J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           0                              J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub. 3                                                                        H H -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                                                                          O                              J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- CH.sub.3                                                                           O                              J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           O                              J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.2                       J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                          CH.sub.2                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                          CH.sub.2                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          CH.sub.2                       J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                          O                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          O                              __________________________________________________________________________

                                      TABLE 4                                     __________________________________________________________________________    General Formula 4                                                                                                            m.p.                           J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.1                                                                            (°C.)                   __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OC.sub.2 H.sub.5                    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                         J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCF.sub.2 H                         J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCF.sub.2 H                         J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCF.sub.2 H                         J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCHF.sub.2                          J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- CH.sub.3                            J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                           J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                    J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           __________________________________________________________________________

                                      TABLE 5                                     __________________________________________________________________________    General Formula 5                                                                                                               m.p.                        J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.1                                                                            Y.sub.3                                                                          (°C.)                __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.3                       J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          H                              J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                       J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.3                       J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          H                              J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           CH.sub.3                       J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                                                                   H                              J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           CH.sub.3                       J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           CH.sub.3                       J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           CH.sub.3                       J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OC.sub.2 H.sub.5                                                                   CH.sub.3                       J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          CH.sub.3                       J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                                                                          H                              J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub. 14                                                                       --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           CH.sub.3                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           H                              J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                                                                          H                              J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- OCH.sub.3                                                                          H                              J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          H                              J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                                                                          CH.sub.3                       J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- CH.sub.3                                                                           H                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                                                                          H                              J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          H                              __________________________________________________________________________

                                      TABLE 6                                     __________________________________________________________________________    General Formula 6                                                                                           7                    m.p.                       J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.2                                                                            Y.sub.2                                                                           (°C.)               __________________________________________________________________________    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           OCH.sub.3                      J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    OC.sub.2 H.sub.5               J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.2 CF.sub.3                                                                  SCH.sub.3                      J.sub.1                                                                         0 CH.sub. 2                                                                        -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    OCF.sub.2 H                    J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    SCF.sub.2 H                    J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    OCH.sub.3                      J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         C.sub.2 H.sub.5                                                                    SCF.sub.2 H                    J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.2 CF.sub.3                                                                  SCH.sub.3                      J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.2 CH.sub.3                                                                  SC.sub.2 H.sub.5               J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.2 CH.sub.3                                                                  SC.sub.2 H.sub.5               J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.2 CH.sub.3                                                                  SCH.sub.3                      J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.2 CF.sub.3                                                                  SC.sub.2 H.sub.5               J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.5                                                                         0 0  0  0  0 H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.2 CF.sub.3                                                                  SCH.sub.3                      J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.2 CH.sub.3                                                                  SC.sub.2 H.sub.5               J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.9                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SC.sub.2 H.sub.5               J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.13                                                                        --                                                                              CH.sub. 2                                                                        O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub. 18                                                                       --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SC.sub.2 H.sub.5               J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- C.sub.2 H.sub.5                                                                    SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- CH.sub.3                                                                           SCH.sub.3                      J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                           SCH.sub.3                      __________________________________________________________________________

                                      TABLE 7                                     __________________________________________________________________________    General Formula 7                                                             J n L  Q  Q.sub.1                                                                          Q.sub.2                                                                         R.sub.1                                                                         R.sub.2                                                                          R.sub.3                                                                          R.sub.4                                                                         R.sub.5                                                                         R.sub.6                                                                          R.sub.7                                                                         R.sub.8                                                                              R.sub.9                                                                          X.sub.3                                                                           m.p. (°C.)               __________________________________________________________________________    J 0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.1                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.1                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         0 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.2                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.2                                                                         1 O  -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.3                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.3                                                                         1 O  -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         0 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.4                                                                         0 O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.4                                                                         1 CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.5                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.6                                                                         0 -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         CH.sub.3                            J.sub.7                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     CH.sub.3                                                                         OCH.sub.3                           J.sub.8                                                                         --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.8                                                                         --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.9                                                                         --                                                                              CH.sub. 2                                                                        -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.10                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.11                                                                        --                                                                              -- -- -- --                                                                              H CH.sub.3                                                                         -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.12                                                                        --                                                                              O  -- -- --                                                                              H -- H  --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.13                                                                        --                                                                              CH.sub.2                                                                         O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.13                                                                        --                                                                              O  O  -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.13                                                                        --                                                                              CH.sub.2                                                                         CH.sub.2                                                                         -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.14                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.14                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- O  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- S  --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- CH.sub.3                            J.sub.15                                                                        --                                                                              -- -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H H -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- O  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- S  --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.16                                                                        --                                                                              CH.sub.2                                                                         -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.16                                                                        --                                                                              O  -- SO.sub.2                                                                         --                                                                              H -- CH.sub.3                                                                         H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.17                                                                        --                                                                              -- -- -- O H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.17                                                                        --                                                                              -- -- -- S H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              H  H --     -- OCH.sub.3                           J.sub.18                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- H  H --                                                                              CH.sub.3                                                                         H --     -- CH.sub.3                            J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.19                                                                        --                                                                              -- -- -- --                                                                              H -- H  H --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- OCH.sub.3                           J.sub.20                                                                        --                                                                              O  -- -- --                                                                              H -- -- --                                                                              --                                                                              -- --                                                                              --     -- CH.sub.3                            J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              CH.sub.2                                                                         -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Cl     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              F      -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              Br     -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              OSO.sub.2 CH.sub.3                                                                   -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              SO.sub.2 N(CH.sub.3).sub.2                                                           -- OCH.sub.3                           J.sub.21                                                                        --                                                                              O  -- -- --                                                                              --                                                                              -- -- --                                                                              --                                                                              -- --                                                                              CO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           __________________________________________________________________________

Formulations

Useful formulations of the compounds of Formula I can be prepared inconventional ways. They include dusts, granules, pellets, solutions,suspensions, emulsions, wettable powders, emulsifiable concentrates andthe like. Many of these may be applied directly. Sprayable formulationscan be extended in suitable media and used at spray volumes of from afew liters to several hundred liters per hectare. High strengthcompositions are primarily used as intermediates for furtherformulation. The formulations, broadly, contain about 0.1% to 99% byweight of active ingredient(s) and at least one of (a) about 0.1% to 20%surfactant(s) and (b) about 1% to 99.9% solid or liquid inertdiluent(s). More specifically, they will contain these ingredients inthe following approximate proportions:

                  TABLE 8                                                         ______________________________________                                                    Active  Weight Percent*                                                       Ingredient                                                                            Diluent(s)                                                                              Surfactant(s)                                   ______________________________________                                        Wettable Powders                                                                            20-90     0-74      1-10                                        Oil Suspensions,                                                                            3-50      40-95     0-15                                        Emulsions, Solutions,                                                         (including Emulsifiable                                                       Concentrates)                                                                 Aqueous Suspension                                                                          10-50     40-84     1-20                                        Dusts         1-25      70-99     0-5                                         Granules and Pellets                                                                        0.1-95    5-99.9    0-15                                        High Strength 90-99     0-10      0-2                                         Compositions                                                                  ______________________________________                                         *Active ingredient plus at least one of a Surfactant or a Diluent equals      100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be presentdepending on the intended use and the physical properties of thecompound. Higher ratios of surfactant to active ingredient are sometimesdesirable, and are achieved by incorporation into the formulation or bytank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook ofInsecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books,Caldwell, N.J., but other solids, either mined or manufactured, may beused. The more absorptive diluents are preferred for wettable powdersand the denser ones for dusts. Typical liquid diluents and solvents aredescribed in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York,1950. Solubility under 0.1% is preferred for suspension concentrates;solution concentrates are preferably stable against phase separation at0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC PublishingCorp. Ridgewood, N.J., as well as Sisely and Wood. "Encyclopedia ofSurface Active Agents", Chemical Publishing Co., Inc., New York, 1964,list surfactants and recommended uses. All formulations can containminor amounts of additives to reduce foaming, caking, corrosion,microbiological growth, etc.

The methods of making such compositions are well known. Solutions areprepared by simply mixing the ingredients. Fine solid compositions aremade by blending and, usually, grinding as in a hammer or fluid energymill. Suspensions are prepared by wet milling (see, for example,Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made byspraying the active material upon preformed granular carriers or byagglomeration techniques. See J. E. Browning, "Agglomeration", ChemicalEngineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer'sHandbook", 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff.

For further information regarding the art of formulation, see forexample:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58,132, 138-140, 162-164, 166, 167 and 169-182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, June 23, 1959, Col. 3,line 66 through Col. 5, line 17 and Examples 1-4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc.,New York, 1961, pp. 81-96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., BlackwellScientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwiseindicated.

EXAMPLE 9 Wettable Powder

    ______________________________________                                        N--[4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                           bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide          80%                                                sodium alkylnaphthalenesulfonate                                                                         2%                                                 sodium ligninsulfonate     2%                                                 synthetic amorphous silica 3%                                                 kaolinite                  13%                                                ______________________________________                                    

The ingredients are blended, hammer-milled until all the solids areessentially under 50 microns, reblended, and packaged.

EXAMPLE 10 Wettable Powder

    ______________________________________                                        N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                          dihydro-2-methyl-benzo[B]thiophene-7-methanesulfon-                           amide-1,1-dioxide            50%                                              sodium alkylnaphthalenesulfonate                                                                           2%                                               low viscosity methyl cellulose                                                                             2%                                               diatomaceous earth           46%                                              ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and then air-milledto produce particles essentially all below 10 microns in diameter. Theproduct is reblended before packaging.

EXAMPLE 11 Granule

    ______________________________________                                        Wettable Powder of Example 10                                                                        5%                                                     attapulgite granules   95%                                                    (U.S.S. 20-40 mesh: 0.84-0.42 mm)                                             ______________________________________                                    

A slurry of wettable powder containing 25% solids is sprayed on thesurface of attapulgite granules in a double-cone blender. The granulesare dried and packaged.

EXAMPLE 12 Extruded Pellet

    ______________________________________                                        1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                      aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                           amide                        25%                                              anhydrous sodium sulfate     10%                                              crude calcium ligninsulfonate                                                                              5%                                               sodium alkylnaphthalenesulfonate                                                                           1%                                               calcium/magnesium bentonite  59%                                              ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about12% water. The mixture is extruded as cylinders about 3 mm diameterwhich are cut to produce pellets about 3 mm long. These may be useddirectly after drying, or the dried pellets may be crushed to pass aU.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S.No. 40 sieve (0.42 mm openings) may be packaged for use and the finesrecycled.

EXAMPLE 13 Low Strength Granule

    ______________________________________                                        1,3-dihydro-N--[(4,6-dimethoxypyrimidin-2-yl)amino--                          carbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                                amide                       0.1%                                              attapulgite granules        99.9%                                             (U.S.S. 20-40 mesh)                                                           ______________________________________                                    

The active ingredient is dissolved in a solvent and the solution issprayed when upon dedusted granules in a double-cone blender. Afterspraying of the solution has been completed, the material is warmed toevaporate the solvent. The material is allowed to cool and thenpackaged.

EXAMPLE 14 Granule

    ______________________________________                                        1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                      aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                           amide                        80%                                              wetting agent                1%                                               crude ligninsulfonate salt (containing                                                                     10%                                              5-20% of the natural sugars)                                                  attapulgite clay             9%                                               ______________________________________                                    

The ingredients are blended and milled to pass through a 100 meshscreen. This material is then added to a fluid bed granulator, the airflow is adjusted to gently fluidize the material, and a fine spray ofwater is sprayed onto the fluidized material. The fluidization andspraying are continued until granules of the desired size range aremade. The spraying is stopped, but fluidization is continued, optionallywith heat, until the water content is reduced to the desired level,generally less than 1%. The material is then discharged, screened to thedesired size range, generally 14-100 mesh (1410-149 microns), andpackaged for use.

EXAMPLE 15 Low Strength Granule

    ______________________________________                                        1,3-dihydro-N--[(4,6-dimethoxypyrimidin-2-yl)amino-                           carbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                                amide                       1%                                                N,N--dimethylformamide      9%                                                attapulgite granules        90%                                               (U.S.S. 20-40 sieve)                                                          ______________________________________                                    

The active ingredient is dissolved in the solvent and the solution issprayed upon dedusted granules in a double cone blender. After sprayingof the solution has been completed, the blender is allowed to run for ashort period and then the granules are packaged.

EXAMPLE 16 Aqueous Suspension

    ______________________________________                                        N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                          bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide          40%                                                polyacrylic acid thickener 0.3%                                               dodecylphenol polyethylene glycol ether                                                                  0.5%                                               disodium phosphate         1%                                                 monosodium phosphate       0.5%                                               polyvinyl alcohol          1.0%                                               water                      56.7%                                              ______________________________________                                    

The ingredients are blended and ground together in a sand mill toproduce particles essentially all under 5 microns in size.

EXAMPLE 17 Solution

    ______________________________________                                        N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                          dihydro-2-methyl-benzo[B]thiophene-7-methanesulfon-                           amide-1,1-dioxide, sodium salt                                                                             5%                                               water                        95%                                              ______________________________________                                    

The salt is added directly to the water with stirring to produce thesolution, which may then be packaged for use.

EXAMPLE 18 High Strength Concentrate

    ______________________________________                                        1,3-dihydro-N--[(4,6-dimethoxypyrimidin-2-yl)amino-                           carbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                                amide                       99%                                               silica aerogel              0.5%                                              synthetic amorphous silica  0.5%                                              ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce amaterial essentially all passing a U.S.S. No. 50 screen (0.3 mmopening). The concentrate may be formulated further if necessary.

EXAMPLE 19 Wettable Powder

    ______________________________________                                        N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                          dihydro-2-methyl-benzo[B]thiophene-7-methanesulfon-                           amide-1,1-dioxide            90%                                              dioctyl sodium sulfosuccinate                                                                              0.1%                                             synthetic fine silica        9.9%                                             ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produceparticles essentially all below 100 microns. The material is siftedthrough a U.S.S. No. 50 screen and then packaged.

EXAMPLE 20 Wettable Powder

    ______________________________________                                        1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                      aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                           amide                        40%                                              sodium ligninsulfonate       20%                                              montmorillonite clay         40%                                              ______________________________________                                    

The ingredients are thoroughly blended, coarsely hammer-milled and thenair-milled to produce particles essentially all below 10 microns insize. The material is reblended and then packaged.

EXAMPLE 21 Oil Suspension

    ______________________________________                                        N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                          bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide          35%                                                blend of polyalcohol carboxylic                                                                          6%                                                 esters and oil soluble petroleum                                              sulfonates                                                                    xylene                     59%                                                ______________________________________                                    

The ingredients are combined and ground together in a sand mill toproduce particles essentially all below 5 microns. The product can beused directly, extended with oils, or emulsified in water.

EXAMPLE 22 Dust

    ______________________________________                                        N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                          bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide          10%                                                attapulgite                10%                                                Pyrophyllite               80%                                                ______________________________________                                    

The active ingredient is blended with attapulgite and then passedthrough a hammer-mill to produce particles substantially all below 200microns. The ground concentrate is then blended with powderedpyrophyllite until homogeneous.

EXAMPLE 23 Oil Suspension

    ______________________________________                                        N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                          dihydro-2-methyl-benzo[B]thiophene-7-methanesul-                              fonamide-1,1-dioxide         25%                                              polyoxyethylene sorbitol hexaoleate                                                                        5%                                               highly aliphatic hydrocarbon oil                                                                           70%                                              ______________________________________                                    

The ingredients are ground together in a sand mill until the solidparticles have been reduced to under about 5 microns. The resultingthick suspension may be applied directly, but preferably after beingextended with oils or emulsified in water.

EXAMPLE 24 Wettable Powder

    ______________________________________                                        1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                      aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                           amide                        20%                                              sodium alkylnaphthalenesulfonate                                                                           4%                                               sodium ligninsulfonate       4%                                               low viscosity methyl cellulose                                                                             3%                                               attapulgite                  69%                                              ______________________________________                                    

The ingredients are thoroughly blended. After grinding in a hammer-millto produce particles essentially all below 100 microns, the material isreblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) andpackaged.

Utility

The compounds of the present invention are active herbicides, havingutility for broad-spectrum pre- and/or post-emergence weed control inareas where complete control of all vegetation is desired, such asaround fuel storage tanks, ammunition depots, industrial storage areas,parking lots, drive-in theaters, billboards, and highway and railroadstructures.

The rates of application for the compounds of the invention aredetermined by a number of factors, including the types of weeds to becontrolled, weather and climate, formulations selected, mode ofapplication, amount of foliage present, etc. In general terms, thesubject compounds should be applied at levels of around 0.05 to 5 kg/ha.the lower rates being suggested for use on lighter soils and/or thosehaving a low organic matter content, of for situations where onlyshort-term persistance is required.

The compounds of the invention may be used in combination with any othercommercial herbicide; examples of which are those of the triazine,triazole, uracil, urea, amide, diphenylether, carbamate and bipyridyliumtypes. The compounds may also be used in combination with mefluidide.

The herbicidal properties of the subject compounds were discovered in anumber of greenhouse tests. The test procedure and results follow.

Test A

Seeds of crabgrass (Digitaria sp.), barnyardgrass (Echinochloacrusgalli), wild oats (Avena fatua), sicklepod (Cassia obtusifolia),morningglory (Ipomoea sp.), cocklebur (Xanthum sp.), sorghum, corn,soybean, cotton rice, sugar beet, rice, wheat and purple nutsedge(Cyperus rotundus) tubers were planted in a growth medium and treatedpre-emergence with the test compounds dissolved in a non-phytotoxicsolvent. At the same time, these crop and weed species were treated witha soil/foilage application. At the time of treatment, the plants rangedin height from 2 to 18 cm. Treated plants and controls were maintainedin a greenhouse for sixteen days, after which all species were comparedto controls and visually rated for response to treatment. The ratings,summarized in Table A, are based on a numerical scale extending from0=no injury, to 10=complete kill. The accompanying descriptive symbolshave the following meanings:

C=chlorosis of necrosis;

G=growth retardation; and

H=formative effects.

The test compounds are referenced in the table of results as follows:

    ______________________________________                                        Compounds                                                                     ______________________________________                                        Compound 1                                                                              ##STR38##                                                           Compound 2                                                                              ##STR39##                                                           Compound 3                                                                              ##STR40##                                                           Compound 4                                                                              ##STR41##                                                           Compound 5                                                                              ##STR42##                                                           Compound 6                                                                              ##STR43##                                                           Compound 7                                                                              ##STR44##                                                           Compound 8                                                                              ##STR45##                                                           Compound 9                                                                              ##STR46##                                                           Compound 10                                                                             ##STR47##                                                           Compound 11                                                                             ##STR48##                                                           Compound 12                                                                             ##STR49##                                                           ______________________________________                                    

                  TABLE A                                                         ______________________________________                                                     Cmpd. 1  Cmpd. 2  Cmpd. 3                                                                              Cmpd. 4                                 Rate kg/ha   0.05     0.05     0.05   0.05                                    ______________________________________                                        POST-EMERGENCE                                                                Morningglory 6C,9G    3C,9G    3C,6H  10C                                     Cocklebur    5C,8G    5C,9G    3C,5G  10C                                     Sicklepod    4C,8G    3C,3H    2C,3G  9C                                      Nutsedge     3C,8G    2G       2C,3G  5G                                      Crabgrass    0        0        2C,5G  3C,8G                                   Barnyardgrass                                                                              0        0        3C,6H  4C,9H                                   Wild Oats    0        0        3C,6G  3C,8G                                   Wheat        0        0        3C,8G  6G                                      Corn         3C,9H    1H       3C,9G  2U,9G                                   Soybean      3C,9G    2C,8G    3H     9C                                      Rice         2C,6G    2G       5C,9G  6C,9G                                   Sorghum      3C,9H    2C,9H    4C,9H  6C,9H                                   Sugar beet   9C       4C,9G    3C,4H  10C                                     Cotton       3C,8H    3C,5G    0      9C                                      ______________________________________                                        PRE-EMERGENCE                                                                 Morningglory 8G       2C,3H    0      9G                                      Cocklebur    2C,5H    2C,2H    --     8H                                      Sicklepod    1C,2G    0        0      2C,7G                                   Nutsedge     2G       0        0      4G                                      Crabgrass    1C       0        2G     2C,5G                                   Barnyardgrass                                                                              0        0        1H     4C,9H                                   Wild Oats    0        0        2C,7G  2C,8H                                   Wheat        4G       3G       2C,8G  3C,9H                                   Corn         2C,8H    0        3C,7H  2U,9G                                   Soybean      2C,8H    0        0      3C,8H                                   Rice         2C,7G    2G       3C,8H  5C,9H                                   Sorghum      3C,8H    3C,8H    3C,9G  5C,9H                                   Sugar beet   9C       3C,8G    0      9C                                      Cotton       8H       1C       0      9G                                      ______________________________________                                                     Cmpd. 5  Cmpd. 6  Cmpd. 7                                                                              Cmpd. 8                                 Rate kg/ha   0.05     0.05     0.05   0.05                                    ______________________________________                                        POST-EMERGENCE                                                                Morningglory 8G       10C      2C,6G  10C                                     Cocklebur    5G       3C,9G    3G     10C                                     Nutsedge     2C,3G    3G       0      3G                                      Crabgrass    3C,7G    3G       0      5G                                      Barnyardgrass                                                                              9C       3C,6H    3C,8H  3C,8H                                   Wild Oats    9C       2C,4G    4C,8G  2C                                      Wheat        10C      3G       9C     9G                                      Corn         9C       4C,9H    4C,9G  3C,9H                                   Soybean      5C,9H    5C,9G    3C,8H  9C                                      Rice         9C       9C       9C     9C                                      Sorghum      9C       5C,9H    5C,9G  5C,9H                                   Sugar beet   3C,7H    9C       3C,7G  5C,9G                                   Cotton       3C,7H    5C,9G    3C,5G  5C,9G                                   Sicklepod    3C,3H    4C,7H    2C,5G  9C                                      ______________________________________                                        PRE-EMERGENCE                                                                 Morningglory 3C,5H    9G       8G     9G                                      Cocklebur    0        5H       2H     8H                                      Nutsedge     0        0        2C     3G                                      Crabgrass    0        0        0      2C,5G                                   Barnyardgrass                                                                              3C,5G    0        1H     2C,6G                                   Wild Oats    8G       2C,3G    5G     2C,5G                                   Wheat        2C,8H    2G       2C,9H  2C,7G                                   Corn         3C,8H    3C,3G    2C,8H  4C,9H                                   Soybean      1C       3C,5H    2C,2H  4C,6H                                   Rice         5C,9H    7H       5C,9H  5C,9H                                   Sorghum      4C,9H    3C,7H    5C,9H  4C,9G                                   Sugar beet   8G       9C       5G     9C                                      Cotton       2G       5G       5G     3C,7G                                   Sicklepod    2C       2C,2H    1C     2C,4G                                   ______________________________________                                                     Cmpd. 9  Cmpd. 10 Cmpd. 11                                                                             Cmpd. 12                                Rate kg/ha   0.05     0.05     0.05   0.05                                    ______________________________________                                        POST-EMERGENCE                                                                Morningglory 3C,9G    3G       9C     10C                                     Cocklebur    2G       3G       2C     5C,9G                                   Nutsedge     5G       0        2C,7G  2C,6G                                   Crabgrass    0        0        2G     2C                                      Barnyardgrass                                                                              0        0        0      0                                       Wild Oats    0        0        0      0                                       Wheat        0        0        0      0                                       Corn         0        0        1H     3C,8H                                   Soybean      5C,9G    3C,8G    5C,9G  5C,9G                                   Rice         0        0        0      0                                       Sorghum      0        0        3G     3C,8H                                   Sugar beet   3C,6G    0        5C,9G  5C,9G                                   Cotton       9C       2G       4C,9G  4C,9G                                   Sicklepod    2C,3G    1C       3C,8G  4C,6G                                   ______________________________________                                        PRE-EMERGENCE                                                                 Morningglory 8G       3G       9G     9G                                      Cocklebur    2H       3G       --     8H                                      Nutsedge     3G       0        5G     0                                       Crabgrass    4G       3G       0      0                                       Barnyardgrass                                                                              0        0        3G     3G                                      Wild Oats    0        0        3G     5G                                      Wheat        0        0        4G     8G                                      Corn         0        3G       2C,7G  9G                                      Soybean      1H       0        2H     3C,7G                                   Rice         0        0        2G     2G                                      Sorghum      0        2G       5G     9G                                      Sugar beet   5G       2G       5C,9G  5C,9G                                   Cotton       2G       0        8G     8G                                      Sicklepod    5G       4G       2C,7G  2C                                      ______________________________________                                    

Test B

Postemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled withWoodstown sandy loam soil. One pan was planted with blackgrass(Alpecurus myosuroides), sugar beets, nutsedge (Cyperus rotundus)tubers, crabgrass (Digitaria sanguinalis), sicklepod (Cassiaobtusifolia), teaweed (Sida spinosa), jimsonweed (Datura stramonium),velvetleaf (Abutilon theophrasti), oil seed rape (Brassica napus), andgiant foxtail (Seraria faberii). The other pan was planted with wheat,cotton, rice, corn, soybean, wild oats (Avena fatua), cocklebur (Xantiumpensylvanicum), morningglory (Ipomoea hederacea), johnsongrass (Sorghumhalepense) and barnyardgrass (Echinochloa crusgalli). The plants weregrown for approximately fourteen days, then sprayed post-emergence withthe chemicals dissolved in a non-phytotoxic solvent.

Preemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled withWoodstown sandy loam soil. One pan was planted with blackgrass, sugarbeets, nutsedge, crabgrass, sicklepod, teaweed, jimsonweed, velvetleaf,oil seed rape, and giant foxtail. The other pan was planted with wheat,cotton, rice, corn, soybeans, wild oats, cocklebur, morningglory,johnsongrass, and barnyardgrass. The two pans were sprayed pre-emergencewith the chemicals dissolved in a non-phytotoxic solvent.

Treated plants and controls were maintained in the greenhouse for 28days, then all treated plants were compared to controls and visuallyrated for plant response utilizing the rating system as described forTest A.

Response ratings are contained in Table B. The data show the potentialutility of several of the compounds tested for selective weed control incrops such as wheat, soybeans and cotton.

                  TABLE B                                                         ______________________________________                                        PRE-EMERGENCE ON                                                              WOODSTOWN SANDY LOAM                                                          ______________________________________                                        Compound 1                                                                    POST-EMERGENCE                                                                Rate g/ha         62       16       4                                         ______________________________________                                        Corn              3G       0        0                                         Wheat             0        0        0                                         Rice              5G       3G       0                                         Soybean           9G       6G       3G                                        Cotton            7G       3G       0                                         Sugar beet        7G       3G       0                                         Rape              --       --       --                                        Crabgrass         0        0        0                                         Johnsongrass      9G       4G       0                                         Blackgrass        0        0        0                                         Barnyardgrass     3G       0        0                                         Nutsedge          5G       2G       0                                         Giant Foxtail     6G       0        0                                         Wild Oats         0        0        0                                         Cocklebur         8G       3G       0                                         Morningglory      9G       8G       3G                                        Teaweed           0        0        0                                         Sicklepod         3G       0        0                                         Jimsonweed        8G       6G       2G                                        Velvetleaf        9G       7G       3G                                        ______________________________________                                        PRE-EMERGENCE                                                                 Rate g/ha         250      62                                                 ______________________________________                                        Corn              2G       0                                                  Wheat             0        0                                                  Rice              7G       4G                                                 Soybean           3G       0                                                  Cotton            7G       2G                                                 Sugar beet        9G       3G                                                 Rape              --       --                                                 Crabgrass         9G       5G                                                 Johnsongrass      8G       4G                                                 Blackgrass        8G       3G                                                 Barnyardgrass     4G       2G                                                 Nutsedge          8G       5G                                                 Giant Foxtail     6G       2G                                                 Wild Oats         0        0                                                  Cocklebur         8G       0                                                  Morningglory      0        0                                                  Teaweed           9G       5G                                                 Sicklepod         10G      6G                                                 Jimsonweed        8G       6G                                                 Velvetleaf        8G       4G                                                 ______________________________________                                        Compound 2                                                                    POST-EMERGENCE                                                                Rate g/ha         62       16       4                                         ______________________________________                                        Corn              0        0        0                                         Wheat             0        0        0                                         Rice              6G       4G       0                                         Soybean           9G       8G       5G                                        Cotton            5G       3G       0                                         Sugar beet        9G       5G       0                                         Rape              --       --       --                                        Crabgrass         3G       0        0                                         Johnsongrass      5G       2G       0                                         Blackgrass        0        0        0                                         Barnyardgrass     3G       0        0                                         Nutsedge          7G       3G       0 -Giant foxtail 7G 4G 0                  Wild Oats         0        0        0                                         Cocklebur         9G       5G       2G                                        Morningglory      9G       6G       3G                                        Teaweed           4G       0        0                                         Sicklepod         6G       3G       0                                         Jimsonweed        8G       4G       2G                                        Velvetleaf        9G       5G       0                                         ______________________________________                                        PRE-EMERGENCE                                                                 Rate g/ha         250      62       16                                        ______________________________________                                        Corn              0        0        0                                         Wheat             2G       0        0                                         Rice              7G       6G       6G                                        Soybean           2C       0        0                                         Cotton            0        0        0                                         Sugar beet        10G      8G       0                                         Rape              --       --       --                                        Crabgrass         9G       8G       6G                                        Johnsongrass      8G       5G       0                                         Blackgrass        8G       4G       0                                         Barnyardgrass     3G       0        0                                         Nutsedge          8G       5G       2G                                        Giant Foxtail     4G       2G       0                                         Wild Oats         0        0        0                                         Cocklebur         3G       0        0                                         Morningglory      3G       0        0                                         Teaweed           9G       5G       0                                         Sicklepod         8G       8G       5G                                        Jimsonweed        9G       6G       0                                         Velvetleaf        8G       3G       0                                         ______________________________________                                        Compound 4.sup.1                                                              POST-EMERGENCE                                                                Rate g/ha      62       16      4      1                                      ______________________________________                                        Corn           100.70   100.60  90.30  80                                     Wheat          0.0      0.0     0.0    0.0                                    Rice           80.0     70.0    30.0   0.0                                    Soybean        100.90   100.90  100.80 70.20                                  Cotton         100.50   100.20  40.0   0.0                                    Sugar beet     100.90   40.90   0.40   0.0                                    Rape           100.100  100.90  100.90 50.40                                  Crabgrass      20.0     0.0     0.0    0.0                                    Johnsongrass   100.90   100.0   60.0   20                                     Blackgrass     100.70   70.0    30.0   0.0                                    Barnyardgrass  70.50    40.0    0.0                                           Nutsedge       40.--    30.0    0.0    0.0                                    Giant Foxtail  50.0     0.0     0.0    0.0                                    Wild Oats      30.0     0.0     0.0    0.0                                    Cocklebur      100.90   60.70   30.0   0.0                                    Morningglory   100.90   40.90   0.90   0.50                                   Teaweed        80.80    50.80   30.0   0.0                                    Sicklepod      100.100  90.90   30.70  0.0                                    Jimsonweed     100.90   90.90   60.70  30.30                                  Velvetleaf     100.100  100.90  100.90 1                                      ______________________________________                                        PRE-EMERGENCE                                                                 Rate g/ha      250      62      16                                            ______________________________________                                        Corn           90.100   40.30   0.0                                           Wheat          30.30    0.0     0.0                                           Rice           100      90.100  40.60                                         Soybean        80.100   60.50   20.0                                          Cotton         40.60    0.50    0.0                                           Sugar beet     90.100   30.100  0.50                                          Rape           100      80.50   30.0                                          Crabgrass      90.60    0.30    0.0                                           Johnsongrass   90.100   90.90   80.60                                         Blackgrass     90.100   70.80   0.40                                          Barnyardgrass  90.100   70.60   20.20                                         Nutsedge       0.0      0.0     0.0                                           Giant Foxtail  100      70.70   0.0                                           Wild Oats      60.40    30.0    0.0                                           Cocklebur      80.90    70.60   0.40                                          Morningglory   90.80    20.30   0.0                                           Teaweed        90.90    50.50   0.0                                           Sicklepod      70.50    30.20   0.0                                           Jimsonweed     90.100   70.90   20.30                                         Velvetleaf     90.100   70.60   20.30                                         ______________________________________                                        Compound 5                                                                    POST-EMERGNCE                                                                 Rate g/ha         62       16       4                                         ______________________________________                                        Corn              80       50       0                                         Wheat             0        0        0                                         Rice              0        0        0                                         Soybean           90       80       60                                        Cotton            60       0        0                                         Sugar beet        70       60       30                                        Rape              100      90       60                                        Crabgrass         0        0        0                                         Johnsongrass      0        0        0                                         Blackgrass        80       0        0                                         Barnyardgrass     0        0        0                                         Nutsedge          0        0        0                                         Giant Foxtail     0        0        0                                         Wild Oats         0        0        0                                         Cocklebur         100      90       70                                        Morningglory      100      90       80                                        Teaweed           50       20       0                                         Sicklepod         0        0        0                                         Jimsonweed        90       80       0                                         Velvetleaf        80       0        0                                         ______________________________________                                        PRE-EMERGENCE                                                                 Rate g/ha         250      62                                                 ______________________________________                                        Corn              80       0                                                  Wheat             0        0                                                  Rice              80       30                                                 Soybean           70       20                                                 Cotton            20       0                                                  Sugar beet        80       20                                                 Rape              90       30                                                 Crabgrass         0        0                                                  Johnsongrass      90       80                                                 Blackgrass        90       80                                                 Barnyardgrass     70       0                                                  Nutsedge          70       20                                                 Giant Foxtail     70       0                                                  Wild Oats         0        0                                                  Cocklebur         90       0                                                  Morningglory      90       0                                                  Teaweed           60       20                                                 Sicklepod         0        0                                                  Jimsonweed        90       50                                                 Velvetleaf        50       0                                                  ______________________________________                                        Compound 6                                                                    POST-EMERGENCE                                                                Rate g/ha         62       16                                                 ______________________________________                                        Corn              70       40                                                 Wheat             50       0                                                  Rice              70       30                                                 Soybean           90       90                                                 Cotton            0        0                                                  Sugar beet        80       70                                                 Rape              90       70                                                 Crabgrass         20       0                                                  Johnsongrass      20       0                                                  Blackgrass        70       0                                                  Barnyardgrass     0        0                                                  Nutsedge          0        0                                                  Giant Foxtail     0        0                                                  Wild Oats         50       0                                                  Cocklebur         0        0                                                  Morningglory      90       60                                                 Teaweed           30       0                                                  Sicklepod         50       0                                                  Jimsonweed        30                                                          Velvetleaf        70       0                                                  ______________________________________                                        PRE-EMERGENCE                                                                 Rate g/ha         250      62                                                 ______________________________________                                        Corn              40       0                                                  Wheat             0        0                                                  Rice              90       70                                                 Soybean           40       0                                                  Cotton            20       0                                                  Sugar beet        80       30                                                 Rape              60       20                                                 Crabgrass         20       0                                                  Johnsongrass      70       30                                                 Blackgrass        90       60                                                 Barnyardgrass     0        0                                                  Nutsedge          30       0                                                  Giant Foxtail     20       0                                                  Wild Oats         0        0                                                  Cocklebur         0        0                                                  Morningglory      0        0                                                  Teaweed           60       0                                                  Sicklepod         50       0                                                  Jimsonweed        50       30                                                 Velvetleaf        50       30                                                 ______________________________________                                        Compound 8                                                                    POST-EMERGENCE                                                                Rate g/ha         62       16       4                                         ______________________________________                                        Corn              100      90       60                                        Wheat             70       0        0                                         Rice              90       30       0                                         Soybean           100      90       90                                        Cotton            90       20       0                                         Sugar beet        70       20       0                                         Rape              100      90       70                                        Crabgrass         60       0        0                                         Johnsongrass      90       90       70                                        Blackgrass        90       80       20                                        Barnyardgrass     60       20       0                                         Nutsedge          0        0        0                                         Giant Foxtail     40       0        0                                         Wild Oats         40       0        0                                         Cocklebur         80       90       30                                        Morningglory      100      100      90                                        Teaweed           90       80       20                                        Sicklepod         90       60       20                                        Jimsonweed        80       50       0                                         Velvetleaf        100      90       40                                        ______________________________________                                        PRE-EMERGENCE                                                                 Rate g/ha         250      62       16                                        ______________________________________                                        Corn              50       0        0                                         Wheat             40       0        0                                         Rice              100      90       50                                        Soybean           70       0        0                                         Cotton            30       0        0                                         Sugar beet        60       0        0                                         Rape              90       20       0                                         Crabgrass         60       30       0                                         Johnsongrass      90       90       30                                        Blackgrass        90       80       30                                        Barnyardgrass     90       50       0                                         Nutsedge          20       0        0                                         Giant Foxtail     90       50       0                                         Wild Oats         80       20       0                                         Cocklebur         60       0        0                                         Morningglory      0        0        0                                         Teaweed           90       50       20                                        Sicklepod         70       20       0                                         Jimsonweed        90       40       0                                         Velvetleaf        80       30       0                                         ______________________________________                                         .sup.1 Note: there are two sets of data for each rate tested.            

What is claimed is:
 1. A compound of the formula ##STR50## wherein J isselected from ##STR51## n is 0 or 1; L is CH₂ or O;R is H or CH₃ ; R₁ isH, F, Cl, Br, CH₃ or OCH₃ ; R₂ is H or C₁ -C₃ alkyl; R₉ is H, OH, C₁ -C₆alkyl, C₁ -C₆ haloalkyl, C₁ -C₆ alkoxyalkyl, C₃ -C₆ alkenyl, C₃ -C₆alkynyl, C₁ -C₆ alkoxy, phenyl, C₃ -C₆ cycloalkyl, C₄ -C₇cycloalkylalkyl, C₁ -C₆ alkylcarbonyl, C₁ -C₆ alkoxycarbonyl, benzyl, C₃-C₄ haloalkenyl, C₃ -C₆ haloalkynyl, C₃ -C₆ alkylcarbonylalkyl, C₃ -C₆alkoxycarbonylalkyl or C₁ -C₄ cyanoalkyl; A is ##STR52## X is CH₃, OCH₃,Cl, Br, OCH₂ CF₃ or OCF₂ H; Y is C₁ -C₃ alkyl, CH₂ F, cyclopropyl,C.tbd.CH, OCH₃, OC₂ H₅, OCH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂, OCH₂ CH₂ F, CF₃,SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CR(OCH₃)₂, ##STR53##CR(OCH₂ CH₃)₂ or OCF₂ H; Z is CH; andprovided that when X is Cl or Br,then Y is OCH₃, OC₂ H₅, NHCH₃, N(CH₃)₂ or OCF₂ H.
 2. A compound of claim1 where Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, CH₂ F or CF₃ ; and L isCH₂.
 3. A compound of claim 2 where J is J₁, or J₇.
 4. A compound ofclaim 3 where R is H; R₁ is H; and X is CH₃ or OCH₃.
 5. A compound ofclaim 1 wherein R is H; R₉ is H or C₁ -C₃ alkyl; X is CH₃ or OCH₃ ; Y IsCH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, CH₂ F, or CF₃.
 6. A composition forthe control of undesirable vegetation consisting essentially of acompound of claim 1 and at least one of (a) a surface active agent, and(b) a solid or liquid diluent.
 7. A composition for the control ofundesirable vegetation consisting essentially of a compound of claim 2and at least one of (a) a surface active agent, and (b) a solid orliquid diluent.
 8. A composition for the control or undesirablevegetation consisting essentially of a compound of claim 3 and at leastone of (a) a surface active agent, and (b) a solid or liquid diluent. 9.A composition for the control of undesirable vegetation consistingessentially of a compound of claim 4 and at least one of (a) a surfaceactive agent, and (b) a solid or liquid diluent.
 10. A composition forthe control of undesirable vegetation consisting essentially of acompound of claim 5 and at least one of (a) a surface active agent, and(b) a solid or liquid diluent.
 11. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 1.12. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim
 2. 13. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 3.14. A method for the control of undesirable vegetation comprisingapplying to the locus of such vegetation an herbicidally effectiveamount of a compound of claim
 6. 15. A method for the control ofundesirable vegetation comprising applying to the locus of suchvegetation an herbicidally effective amount of a compound of claim 5.